4. Both xenon (Xe) and argon (Ar) are monoatomic noble gases. Watson predicts that Xe is a liquid and Ar is a gas at atmospheric pressure and a temperature of 120 K. Crick states that both should be gases. Upon reviewing the literature, it turns out that Watson is correct. Explain why Watson is correct and propose the principles that Crick was using to make his prediction.

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CH 115 Recitation
Name:
Both xenon (Xe) and argon (Ar) are monoatomic noble gases. Watson predicts that Xe is a liquid and Ar is a
gas at atmospheric pressure and a temperature of 120 K. Crick states that both should be
reviewing the literature, it turns out that Watson is correct. Explain why Watson is correct and propose the
principles that Crick was using to make his prediction.
4.
gases. Upon
Si gorlexhoW nolsloe
5. Given that the boiling point of methanol (CH3OH) is 65°C and methyl mercaptan (CH;SH) is 6°C. You
should predict that methyl mercaptan has the higher boiling point on the basis of greater London Forces, but
the observed trend is opposite of this prediction. Explain why you don't always use one type of
intermolecular force to make a prediction.
6. Given: Kr boils at 120.9 K and Cl2 boils at 238 K. Both would be considered non-polar and the London
Forces are predicted to suggest the opposite boiling point trend (Kr has 83 electrons, Cl2 has 34 electrons).
Thus, there must be something other than just the intermolecular forces involved. Draw a picture of the two
species and think about how the drawings might give a clue. Have the group describe the ideas generated.
7. The molecule dibromoethene (C2H2B12) has a cis and trans form. Draw these molecules and label them as
polar or nonpolar. Why is one polar and the other nonpolar?
Transcribed Image Text:CH 115 Recitation Name: Both xenon (Xe) and argon (Ar) are monoatomic noble gases. Watson predicts that Xe is a liquid and Ar is a gas at atmospheric pressure and a temperature of 120 K. Crick states that both should be reviewing the literature, it turns out that Watson is correct. Explain why Watson is correct and propose the principles that Crick was using to make his prediction. 4. gases. Upon Si gorlexhoW nolsloe 5. Given that the boiling point of methanol (CH3OH) is 65°C and methyl mercaptan (CH;SH) is 6°C. You should predict that methyl mercaptan has the higher boiling point on the basis of greater London Forces, but the observed trend is opposite of this prediction. Explain why you don't always use one type of intermolecular force to make a prediction. 6. Given: Kr boils at 120.9 K and Cl2 boils at 238 K. Both would be considered non-polar and the London Forces are predicted to suggest the opposite boiling point trend (Kr has 83 electrons, Cl2 has 34 electrons). Thus, there must be something other than just the intermolecular forces involved. Draw a picture of the two species and think about how the drawings might give a clue. Have the group describe the ideas generated. 7. The molecule dibromoethene (C2H2B12) has a cis and trans form. Draw these molecules and label them as polar or nonpolar. Why is one polar and the other nonpolar?
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