4. Air in a piston/cylinder assembly at 200 kPa and 500 K is expanded in a constant-pressureprocess to twice the initial volume, state 2, as shown in Figure below. The piston is then lockedwith a pin, and heat is transferred to a final temperature of 600 K. Find P, T, and h for states 2 and3, and find the work and heat transfer in both processes. (15 pt)PoAir00

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Answered: 4. Air in a piston/cylinder assembly at…

Physical Chemistry

2nd Edition

ISBN:9781133958437

Author:Ball, David W. (david Warren), BAER, Tomas

Publisher:Ball, David W. (david Warren), BAER, Tomas

Chapter2: The First Law Of Thermodynamics

Section: Chapter Questions

Problem 2.30E: A piston reversibly and adiabatically contracts 3.88 moles of ideal gas to one-tenth of its original...

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Similar questions

In a constant-pressure calorimeter that is, one that expands or contracts if the volume of the system changes, 0.145 mole of an ideal gas contracts slowly from 5.00 L to 3.92 L. If the initial temperature of the gas is 0.0 C, calculate the U and w for the process.
Many compressed gases come in large,heavy metal cylindersthat are so heavy that they need a special cart to move them around. An80.0-Ltank ofnitrogen gas pressurized to 172 atm is left in the sun and heats from its normal temperature of 20.0C to 140.0C. Determine a the final pressureinsidethe tank and b the work, heat, and U of the process. Assume that behavior is ideal and the heatcapacity of diatomic nitrogenis 21.0J/mol.K.
A 5-mmdiameter hailstone has a terminal velocity of10.0m/s. Assuming its mass is6.031025 kg and all of its kinetic energy turns into heat, calculate the temperaturechangeof the hailstone when it hits the ground and stops. The heat capacity of ice is 2.06J/g.K.
In the 1880s, Frederick Trouton noted that the enthalpy of vaporization of 1 mol pure liquid is approximately 88 times the boiling point, Tb, of the liquid on the Kelvin scale. This relationship is called Troutons rule and is represented by the thermochemical equation liquid gas H = 88 Tb, joules Combined with an empirical formula from chemical analysis, Troutons rule can be used to find the molecular formula of a compound, as illustrated here. A compound that contains only carbon and hydrogen is 85.6% C and 14.4% H. Its enthalpy of vaporization is 389 J/g, and it boils at a temperature of 322 K. (a) What is the empirical formula of this compound? (b) Use Troutons rule to calculate the approximate enthalpy or vaporization or one mole of the compound. Combine the enthalpy of vaporization per mole with that same quantity per gram to obtain an approximate molar mass of the compound. (c) Use the results of parts (a) and (b) to find the molecular formula of this compound. Remember that the molecular mass must be exactly a whole-number multiple of the empirical formula mass, so considerable rounding may be needed.
The enthalpy of vaporization for water is 40.65 kJ mol-1. As a design engineer for a project in a desert climate, you are exploring the option of using evaporative cooling. (a) If the air has an average volumetric heat capacity of 0.00130 J cm-3 K-1, what is the minimum mass of water that would need to evaporate in order to cool a 5 m? 5 m room with a 3 m ceiling by 5°F using this method? (b) Is this a spontaneous or nonspontaneous process?
On complete combustion at constant pressure, a 1.00-L sample of a gaseous mixture at 0C and 1.00 atm (STP) evolves 75.65 kJ of heat. If the gas is a mixture of ethane (C2H6) and propane (C3H8), what is the mole fraction of ethane in the mixture?
If the heat capacity varies withtemperature, abetter form ofequation 2.9 isto solve q=TiTfnCT-t A 50.0-g sample of white phosphorus is heated from 298 K to 350K. If its molar heat capacity is CT- = 56.990.1202T J/mol.K, how much heat is needed?
A piston reversibly and adiabatically contracts 3.88 moles of ideal gas to one-tenth of its original volume, thenexpands back to the original conditions. It does thisa total of five times. If the initial and final temperatures both are 27.5C, calculatea thetotal work andb thetotal U forthe overall process.
Use the data in Table 2.2 to determine Hp T for Ar at 0C and 1atm. Make any reasonable assumptions necessary.
Use the two appropriate values of R to determine a conversion between L. atm and J.
The Dieterici equation of state for one mole of gas is p=RTe-aVRTV-b Where a and b are constants determined experimentally. For NH3g, a = 10.91 atm. L2 and b = 0.0401 L. Plot the pressure of the gas as the volume of 1.00 mol of NH3g expands from 22.4 L to 50.0 L at 273 K, and numerically determine the work done by the gas by measuring the area under the curve.
Calculate the specific heat of a material if 288J of energy were required to heat 50.5g of the material from 298K to 330K. What are the units?

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