4. A galvanic cell consisting of a magnesium electrode and a standard hydrogen electrode is constructed. The cell generates a voltage, Ecell, of 2.099 V. The standard reduction potential for the two half-cell reactions are as follows: Mg²+ (aq) + 2e → Mg (s) 2H+ (aq) + 2e → H₂ (g) -2.38 V OV (i) Determine the standard cell potential, Eºcell. (ii) Assuming a Mg²+ (aq) concentration of 1 mol dm³ and a H₂ (g) pressure of 1 atm, calculate the theoretical pH of the cell. You may use concentrations/partial pressures in place of activities.

4. A galvanic cell consisting of a magnesium electrode and a standard hydrogen electrode is constructed. The cell generates a voltage, Ecell, of 2.099 V. The standard reduction potential for the two half-cell reactions are as follows: Mg²+ (aq) + 2e → Mg (s) 2H+ (aq) + 2e → H₂ (g) -2.38 V OV (i) Determine the standard cell potential, Eºcell. (ii) Assuming a Mg²+ (aq) concentration of 1 mol dm³ and a H₂ (g) pressure of 1 atm, calculate the theoretical pH of the cell. You may use concentrations/partial pressures in place of activities.

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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