Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Solve question 4
![### Transcription for Educational Use
#### Questions
3) Why does the (R,R)-1,2-diaminocyclohexane form a solid complex with L-tartaric acid while the (S,S)-1,2-diaminocyclohexane does not? (*Hint: redraw the reaction scheme from the bottom of page 1 of this lab and use this in your explanation*).
4) The enantiomer of L-tartaric acid is D-tartaric acid. Draw the structure of D-tartaric acid, and label each chiral carbon as R or S.
5) Which enantiomer of *trans*-1,2-diaminocyclohexane would you expect that the D-tartaric acid would form a solid complex with? Explain.
#### Diagram Explanation
The diagram depicts a chemical reaction involving (R,R)-1,2-diaminocyclohexane and tartaric acid. The structures in the diagram are as follows:
- **Left Side**:
- Shows (R,R)-1,2-diaminocyclohexane with two amine groups (NH₂) on a cyclohexane ring.
- Tartaric acid structure with two hydroxyl groups (OH) and two carboxylic acid groups (COOH).
- **Reaction Arrow**:
- Indicates the formation of products on the right side.
- **Right Side**:
- Two complex structures are formed, each with tartaric acid coordinating with the 1,2-diaminocyclohexane.
- The product labeled (s) and (aq) suggests a solid complex and an aqueous solution form, respectively.
The diagram illustrates the stereochemical interactions required for the formation of a solid complex.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fcf76ebb0-a1fb-4e27-be44-e5f7107968b4%2Fd2275841-7eb5-4ee8-8cbb-2e956401213f%2Ffycqgzt_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Transcription for Educational Use
#### Questions
3) Why does the (R,R)-1,2-diaminocyclohexane form a solid complex with L-tartaric acid while the (S,S)-1,2-diaminocyclohexane does not? (*Hint: redraw the reaction scheme from the bottom of page 1 of this lab and use this in your explanation*).
4) The enantiomer of L-tartaric acid is D-tartaric acid. Draw the structure of D-tartaric acid, and label each chiral carbon as R or S.
5) Which enantiomer of *trans*-1,2-diaminocyclohexane would you expect that the D-tartaric acid would form a solid complex with? Explain.
#### Diagram Explanation
The diagram depicts a chemical reaction involving (R,R)-1,2-diaminocyclohexane and tartaric acid. The structures in the diagram are as follows:
- **Left Side**:
- Shows (R,R)-1,2-diaminocyclohexane with two amine groups (NH₂) on a cyclohexane ring.
- Tartaric acid structure with two hydroxyl groups (OH) and two carboxylic acid groups (COOH).
- **Reaction Arrow**:
- Indicates the formation of products on the right side.
- **Right Side**:
- Two complex structures are formed, each with tartaric acid coordinating with the 1,2-diaminocyclohexane.
- The product labeled (s) and (aq) suggests a solid complex and an aqueous solution form, respectively.
The diagram illustrates the stereochemical interactions required for the formation of a solid complex.
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