4)- Convert the sawhorse structure below to the appropriate fisher projection. Determine the relationship of the mirror image of compound A by using the symbols, M- mesomeric, S-same, E enantiomeric, D- diastereomeric). Importantly, in solving all of the problems, make sure that you place the lowest priority groups in the two vertical positions in your final display. Show all manipulations (e.g., bond rotations and molecular movements) as to how you were able to determine all relationships for full credit. "Underline all of your Answers within the most appropriate location on this sheet". Mirror image relationship of A:

4)- Convert the sawhorse structure below to the appropriate fisher projection. Determine the relationship of the mirror image of compound A by using the symbols, M- mesomeric, S-same, E enantiomeric, D- diastereomeric). Importantly, in solving all of the problems, make sure that you place the lowest priority groups in the two vertical positions in your final display. Show all manipulations (e.g., bond rotations and molecular movements) as to how you were able to determine all relationships for full credit. "Underline all of your Answers within the most appropriate location on this sheet". Mirror image relationship of A:

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Referring to (2R,3S)-butan-1,2.3.4-tetraol.. a. Draw its 2D structure, Newman projection formula (eclipsed and staggered (both gauche & anti) and and Fischer projection formula. b. Using its Fischer projection, how many stereoisomers are possible? Draw the corresponding enantiomer and diastereomers (label as I, II, etc). Which pairs are enantiomers? diastereomers? Erythro? Threo? Meso compound/s? c. Using the projection formula, draw an energy diagram for all rotamers starting from the high energy conformer.
A)Circle all of the stereo centers in MDMA. B) assign the absolute stereochemistry (R or S) for each stereo center
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Part A 1. Determine the absolute configuration (R or S) of the stereogenic centre in compounds (1) & (II) below. (i) HO H H₂C CH 3 Br H (II) HO 2. A compound may have a number of possible stereoisomers which is determined with the formula 2 (n = number of stereocentres). The compound (-)-menthone (below) is a Natural Product found in peppermint. Use the formula given to determine the number of possible stereoisomers in this compound can have. I CHO H CH₂CH3 CH(CH3)2
(a) Re-draw the following molecule with the CH2CH3 group on the ladder 1. H. H2 CF H3C H2 CH2 H;C Is the molecule in part (a) the same molecule or the enantiomer of the following. Circle your answer Explain your answer CH3 CH2 H,C SAME MOLECULE CH3 ENANTIOMER H2
Your answer is incorrect. Try again. Which staggered Newman projection(s), looking down the C-2-C-3 bond (C-2 in front and C-3 in back), illustrates the following boxed compound? H₂C CH₂CH3 CI CH3 I H₂C H I, II and III II and V I and III CH₂CH3 CH3 IV H₂C IV only None of these choices. II CH₂CH3 CH3 CH3 H H * H H V CH 3 H CH₂CH3 III CH(CH3)CHCICH 3
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3. Consider the following compound, which is a derivative of cholesterol. HO Identify all asymmetric carbons and assign their absolute configuration. Write the configuration directly next to each asymmetric carbon in the above image.
3. Examine the two chair conformations below and (a) generate their corresponding dash- wedge diagrams, as well as (b) name each compound. When applicable, indicate the R/S absolute configuration in the IUPAC name. Dash-wedge diagram Chair conformation IUPAC name
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