Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**34. Identify the major and minor products for each of the following E2 reactions:**
**Diagrams Explanation:**
Each part (a-f) shows an organic molecule with a leaving group (halogen) undergoing an E2 (bimolecular elimination) reaction. The reactions prompt questions about the major and minor products formed.
- **(a)** A cyclohexane ring with a chlorine (Cl) substituent reacts with sodium ethoxide (NaOEt).
- **(b)** A cyclohexane ring with a chlorine (Cl) substituent reacts with potassium tert-butoxide (t-BuOK).
- **(c)** A linear alkane chain with an iodine (I) substituent reacts with sodium hydroxide (NaOH).
- **(d)** A linear alkane chain with an iodine (I) substituent reacts with potassium tert-butoxide (t-BuOK).
- **(e)** A cyclohexane ring with a bromine (Br) substituent reacts with potassium tert-butoxide (t-BuOK).
- **(f)** A cyclohexane ring with a bromine (Br) substituent reacts with potassium tert-butoxide (t-BuOK), with the Br connected via a wedge, implying stereochemistry.
**Note:** These E2 reactions typically result in the formation of alkenes. The major product often follows Zaitsev's rule, favoring the more substituted alkene, except when steric hindrance or special conditions apply.
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