33. You have a laser (a monochromatic light source) and want to estimate the wavelength. You decide to use a reflective diffraction grating to do this. The light is incident on the grating at 20 degrees with respect to normal. Using a grating with a groove distance of 5 um, the first-order diffraction, is found at an angle of -12.5 degrees. Determine the wavelength of the source. a) 500 nm b) 628 nm c) 808 nm d) 946 nm e) None of the above

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33. You have a laser (a monochromatic light source) and want to estimate the wavelength. You
decide to use a reflective diffraction grating to do this. The light is incident on the grating at 20
degrees with respect to normal. Using a grating with a groove distance of 5 um, the first-order
diffraction, is found at an angle of -12.5 degrees. Determine the wavelength of the source.
a) 500 nm
b) 628 nm
c) 808 nm
d) 946 nm
e) None of the above
34. In Raman spectrometry, Stokes lines have
a) lower energy than that of anti-Stokes scattering.
b) equal energy to that of anti-Stokes scattering.
) higher energy than that of anti-Stokes scattering
d) none of the above
35. Upon ionization of phenol in aqueous solution, maximal UV absorbance changes to longer
wavelength.
a) True
b) False
36. It takes longer time to observe fluorescence than phosphorescence.
a) True
b) False
37. The vibrational motion of C-H stretching in ethylene as in the figure
can be detected by
a) IR.
b) Raman.
c) IR and Raman.
d) None of the above.
38. In a chromatographic experiment, two components elute with retention times of 11.52 and
12.76 minutes, respectively. The half-height widths of the peaks were determined to be 0.37
and 0.42 minutes, respectively. Assuming Gaussian peak shapes, estimate the resolution
between the two peaks.
a) 3.0
b) 3.1
c) 3.2
d) 16
e) None of the above.
Transcribed Image Text:33. You have a laser (a monochromatic light source) and want to estimate the wavelength. You decide to use a reflective diffraction grating to do this. The light is incident on the grating at 20 degrees with respect to normal. Using a grating with a groove distance of 5 um, the first-order diffraction, is found at an angle of -12.5 degrees. Determine the wavelength of the source. a) 500 nm b) 628 nm c) 808 nm d) 946 nm e) None of the above 34. In Raman spectrometry, Stokes lines have a) lower energy than that of anti-Stokes scattering. b) equal energy to that of anti-Stokes scattering. ) higher energy than that of anti-Stokes scattering d) none of the above 35. Upon ionization of phenol in aqueous solution, maximal UV absorbance changes to longer wavelength. a) True b) False 36. It takes longer time to observe fluorescence than phosphorescence. a) True b) False 37. The vibrational motion of C-H stretching in ethylene as in the figure can be detected by a) IR. b) Raman. c) IR and Raman. d) None of the above. 38. In a chromatographic experiment, two components elute with retention times of 11.52 and 12.76 minutes, respectively. The half-height widths of the peaks were determined to be 0.37 and 0.42 minutes, respectively. Assuming Gaussian peak shapes, estimate the resolution between the two peaks. a) 3.0 b) 3.1 c) 3.2 d) 16 e) None of the above.
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