30. Use the phase diagram of methane to answer the following questions. (a) What is the normal boiling point of methane? (b) Over what pressure range does solid methane sublime? (c) Above what temperature does liquid methane not exist? 10% 10² 10 1 10-1 10-2 304 Solid 233 Liquid 1 Supercritical Quid Gas -100 Temperature (0) 0 100 molecula

30. Use the phase diagram of methane to answer the following questions. (a) What is the normal boiling point of methane? (b) Over what pressure range does solid methane sublime? (c) Above what temperature does liquid methane not exist? 10% 10² 10 1 10-1 10-2 304 Solid 233 Liquid 1 Supercritical Quid Gas -100 Temperature (0) 0 100 molecula

Introductory Chemistry: A Foundation

9th Edition

ISBN:9781337399425

Author:Steven S. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Donald J. DeCoste

Chapter14: Liquids And Solids

Section: Chapter Questions

Problem 37QAP

See similar textbooks

Similar questions

Define critical temperature and critical pressure. In terms of the kinetic molecular theory, why is it impossible for a substance to exist as a liquid above its critical temperature?
The following data are the equilibrium vapor pressure of limonene, C10H16, at various temperatures. (Limonene is used as a scent in commercial products.) (a) Plot these data as ln P versus 1/T so that you have a graph resembling the one in Figure 11.13. (b) At what temperature does the liquid have an equilibrium vapor pressure of 250 mm Hg? At what temperature is it 650 mm Hg? (c) What is the normal boiling point of limonene? (d) Calculate the molar enthalpy of vaporization for limonene using the Clausius-Clapeyron equation.
The molecular mass of butanol, C4H9OH, is 74.14; that of ethylene glycol, CH2(OH)CH2OH, is 62.08, yet their boiling points are 117.2 C and 174 C, respectively. Explain the reason for the difference.
A 1.50-g sample of methanol (CH3OH) is placed in an evacuated 1.00-L container at 30 C. (a) Calculate the pressure in the container if all of the methanol is vaporized. (Assume the ideal gas law, PV = nRT.) (b) The vapor pressure of methanol at 30 C is 158 torr. What mass of methanol actually evaporates? Is liquid in equilibrium with vapor in the vessel?
A mixture of toluene (bp110.8C) and water is steam distilled. Visual inspection of the distillate reveals that there is a greater volume of toluene than water present, yet water (bp100C) has the higher vapor pressure. Explain this observation.
Equilibrium vapor pressures of benzene, C6H6, at various temperatures are given in the table. (a) What is the normal boiling point of benzene? (b) Plot these data so that you have a graph resembling the one in Figure 11.12. At what temperature does the liquid have an equilibrium vapor pressure of 250 mm Hg? At what temperature is the vapor pressure 650 mm Hg? (c) Calculate the molar enthalpy of vaporization for benzene using the ClausiusClapeyron equation.
Of the four general types of solids, which one(s) (a) are generally low-boiling? (b) are ductile and malleable? (c) are generally soluble in nonpolar solvents?
8.87 Use the vapor pressure curves illustrated here to answer the questions that follow. (a) What is the vapor pressure of ethanol (C2H5OH) at 60°C? (b) Considering only carbon disulfide (CS2) and ethanol, which has the stranger intermolecular forces in the liquid state? (c) At what temperature does heptane (C7H16) have a vapor pressure of 500 mm Hg? (d) What are the approximate normal boiling pains of each of the three substances? (e) At a pressure of 400 mm Hg and a temperature of 70°C, is each substance a liquid, a gas, or a mixture of liquid and gas?
Two molecules that contain the same number of each kind of atom but [hat have different molecular structures are said to he isomers of each other. For example, both ethyl alcohol and dimethyl ether (shown below} have the formula C2H6Oand are isomers; Based on considerations of intermolecular forces. which substance would you expect to be more volatile? Which would you expect 10have the higher boiling point? Explain. methyl ether hyl alcohol msp;CH3OCH3CH3CH2OH
Explain why evaporation leads to cooling of the liquid.
Of the four general types of solids, which one(s) (a) are generally insoluble in water? (b) have very high melting points? (c) conduct electricity as solids?