3.24 On the basis of ionic charge and ionic radii given in Table 3.4, predict crystal structures for the following materials: (a) Csl. (b) NIO, (c) KI (d) NiS. Justify your selections. 3.25 Which of the cations in Table 3.4 would you predict to form iodides having the cesium chloride crystal structure? Justify your choices.

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Table 3.4
lonic Radii for Several
Cations and Anions
for a Coordination
Number of 6
Cation
A1³+
Ba²+
Ca²+
Cs+
Fe²+
Fe³+
K+
Mg²+
Mn²+
Na+
N₁²+
Si4+
Ti4+
Ionic Radius (nm)
0.053
0.136
0.100
0.170
0.077
0.069
0.138
0.072
0.067
0.102
0.069
0.040
0.061
Anion
Br
CIT
F
I™
0²-
S²-
Ionic Radius (nm)
0.196
0.181
0.133
0.220
0.140
0.184
Transcribed Image Text:Table 3.4 lonic Radii for Several Cations and Anions for a Coordination Number of 6 Cation A1³+ Ba²+ Ca²+ Cs+ Fe²+ Fe³+ K+ Mg²+ Mn²+ Na+ N₁²+ Si4+ Ti4+ Ionic Radius (nm) 0.053 0.136 0.100 0.170 0.077 0.069 0.138 0.072 0.067 0.102 0.069 0.040 0.061 Anion Br CIT F I™ 0²- S²- Ionic Radius (nm) 0.196 0.181 0.133 0.220 0.140 0.184
Ceramic Crystal Structures
3.24 On the basis of ionic charge and ionic radii given in Table 3.4. predict crystal structures for the
following materials:
(a) Csl.
(b) NiO,
(c) KI
(d) NiS.
Justify your selections.
3.25 Which of the cations in Table 3.4 would you predict to form iodides having the cesium chloride
crystal structure? Justify your choices.
Transcribed Image Text:Ceramic Crystal Structures 3.24 On the basis of ionic charge and ionic radii given in Table 3.4. predict crystal structures for the following materials: (a) Csl. (b) NiO, (c) KI (d) NiS. Justify your selections. 3.25 Which of the cations in Table 3.4 would you predict to form iodides having the cesium chloride crystal structure? Justify your choices.
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