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3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

Chemistry
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ (c) HOCH₂ (1) (S)-CH₂(CH₂)₂CHCH₂ + C₂H₁ (k) CH₂O OH 11 N(CPH)2 PhCO, O,CPh C₂Hs CH₂O (CH)₂CHBr + OCH₂ H CH,CO,H HCI CH₂OH - (PhO),PCH, F DMF, 20°C 10 min C₂H₁₂O₂Cl BB₂, -78°C 0°C, 1 h CH₂Cl₂ (OCH3)3 Et₂N EN*Cr C38H28N5O,1 1) NaOH 2) H* NCH₂CH heat CH₁3Cl C₁1H₁202 48% HBr (b) C₁7H₁7NO₂ CHJ(CH,),CH,OH + CICH,OCH, (d) C₂H₂O₂CCH₂CHCO₂C₂H₁ OH (1) CH₂CHCH₂OH (h) (₁) C₁3H₁3PO3 CH₂ (1) Ph CO, CH HOCH₂ HOCH₂ H PPh₂ CC14 C₂H₂O₂C H1) p-toluenesulfonyl chloride OH 2) PhS™ Na* 1) Ph₂P, HN₂ 2) DEAD C10H₁7CI CO₂H 'H 1) CH₂SO₂CI pyridine EIN(+Pr)₂ CH₂Cl₂ 2) Na S HMPA +- BuOH DCC, DMAP C₂H₁3N₂O4 C16H18S C₂H1802 C14H12O₂S C10H1604
Transcribed Image Text:3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ (c) HOCH₂ (1) (S)-CH₂(CH₂)₂CHCH₂ + C₂H₁ (k) CH₂O OH 11 N(CPH)2 PhCO, O,CPh C₂Hs CH₂O (CH)₂CHBr + OCH₂ H CH,CO,H HCI CH₂OH - (PhO),PCH, F DMF, 20°C 10 min C₂H₁₂O₂Cl BB₂, -78°C 0°C, 1 h CH₂Cl₂ (OCH3)3 Et₂N EN*Cr C38H28N5O,1 1) NaOH 2) H* NCH₂CH heat CH₁3Cl C₁1H₁202 48% HBr (b) C₁7H₁7NO₂ CHJ(CH,),CH,OH + CICH,OCH, (d) C₂H₂O₂CCH₂CHCO₂C₂H₁ OH (1) CH₂CHCH₂OH (h) (₁) C₁3H₁3PO3 CH₂ (1) Ph CO, CH HOCH₂ HOCH₂ H PPh₂ CC14 C₂H₂O₂C H1) p-toluenesulfonyl chloride OH 2) PhS™ Na* 1) Ph₂P, HN₂ 2) DEAD C10H₁7CI CO₂H 'H 1) CH₂SO₂CI pyridine EIN(+Pr)₂ CH₂Cl₂ 2) Na S HMPA +- BuOH DCC, DMAP C₂H₁3N₂O4 C16H18S C₂H1802 C14H12O₂S C10H1604
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