3.1. Give the products that would be expected to be formed under the specifiedreaction conditions. Be sure to specify all aspects of the stereochemistry.(a)CH₂CH₂(c)HOCH₂(1)(S)-CH₂(CH₂)₂CHCH₂ + C₂H₁(k)CH₂OOH11N(CPH)2PhCO, O,CPhC₂HsCH₂O(CH)₂CHBr +OCH₂HCH,CO,HHCICH₂OH-(PhO),PCH, FDMF, 20°C10 minC₂H₁₂O₂ClBB₂, -78°C0°C, 1 hCH₂Cl₂(OCH3)3Et₂NEN*CrC38H28N5O,11) NaOH2) H*NCH₂CH heatCH₁3ClC₁1H₁20248% HBr(b)C₁7H₁7NO₂CHJ(CH,),CH,OH + CICH,OCH,(d)C₂H₂O₂CCH₂CHCO₂C₂H₁OH(1)CH₂CHCH₂OH(h)(₁)C₁3H₁3PO3CH₂(1)PhCO, CHHOCH₂HOCH₂HPPh₂CC14C₂H₂O₂CH1) p-toluenesulfonyl chlorideOH2) PhS™ Na*1) Ph₂P, HN₂2) DEADC10H₁7CICO₂H'H1) CH₂SO₂CIpyridineEIN(+Pr)₂CH₂Cl₂2) Na SHMPA+- BuOHDCC,DMAPC₂H₁3N₂O4C16H18SC₂H1802C14H12O₂SC10H1604

Answered: Image /qna-images/answer/19b7abcb-ff19-4292-9844-e0da1b1cf684.jpg

3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

3.1. Give the products that would be expected to be formed under the specified reaction conditions. Be sure to specify all aspects of the stereochemistry. (a) CH₂CH₂ HCI CH₂OH C,H₁₂O₂Cl (b) CH₂(CH₂) CH₂OH + CICH₂OCH, EtN(/Pr)₂ CH₂Cl₂ C₂H₁80₂

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

See similar textbooks

Similar questions

(a) Illustrate the following name reactions giving a chemical equation in each case :(i) Clemmensen reaction (ii) Cannizzaro’s reaction(b) Describe how the following conversions can be brought about :(i) Cyclohexanol to cyclohexan-1-one (ii) Ethylbenzene to benzoic acid(iii) Bromobenzene to benzoic acid
The following two sets of reactions [(a) and (b)] show possibilities for arrow pushing in individual reaction steps. Identify which is wrong and explain why. Then using arrow pushing correctly, label which molecule is the nucleophile and which is the electrophile. (b) (a) H-CI: . .- :O: :Ö: H3C H3C CH3 C=N C-CH3 + :CI: H3C CH3 H3C CH2 H3C H3C ":C=N: H-CI: H3C I+ C-CH3 + :C: H3C H3C CH3 CH3 C=N: C-CH2 H3C > H3C H3C C=N:
Account for the following :(a) The dipole moment of chlorobenzene is lower than that of cyclohexyl chloride.(b) Alkyl halides, though polar, are immiscible with water.(c) Grignard’s reagents should be prepared under anhydrous conditions.
1. One version of canola oil is (C15H29CO2)3C3H5. (a) Write the transesterification chemical equation (similar to Eq. 12-7) for canola oil. (b) How much canola oil will be required to produce one ton of biodiesel? 2. Write the chemical reaction equations for hexene (C6H12), butanol (C4H9OH), and heptane (C7H₁6) for the Fischer-Tropsch synthesis process. If appropriate, the value of "n" must be used in a chemical equation.
Hh.182.
When 3-methyl-1-butene is reacted with 9-borabicyclo[3.3.1]nonane, the "1-ol" product is formed. What is the detailed reactin scheme for the transformation? Describe the purification procedure.
(a) Write the products of following reactions. Give mechanism with proper stereochemistry? (2 x 2.5 = 5) (ii) Me Δ Δ CN
5.40. Give plausible products (or just one product) for each of the following reactions, or tell if no reaction is expected. (a) PDSO, + MgS > (b) (CH,),Hg + CaF, → 1. 1.
3. following reactions. (a) Draw the product(s) including its(their) stereochemistry in each of the H20 (6) Br cI :8=c-H (i) 1. SOCI, OH 2. CH300 HBr (aq.) (iv) (b) Draw a stepwise mechanism for the formation of products in the reaction below. OH Br (c) Device a synthesis of the product from the given starting material for the following transformation. More than one step is required. ÇI HO.
46
A reasonable synthesis for each of the following compounds
(a) For the reaction of 1-methoxy-4-methylbenzene with CH3C(O)CI in the presence of AICI3, describe the bonding and electron distribution in 1-methoxy- 4-methylbenzene, formation and structure of the electrophile in the reaction, and the most stable intermediate responsible for the end product. i H3C1 CI, AICI 3 Me- -OMe 1-methoxy-4-methylbenzene (b) Use phenol as the substrate, propose a synthetic scheme to produce 2-allyl-4-bromophenol (Mechanism not required). Br OH OH phenol 2-allyl-4-bromophenol (c) Propose a synthesis of Compound A starting from benzaldehyde and other necessary reagents of your choice (Mechanism not required). OH CHO CI. Compound A benzaldehyde (d) For the given 13C NMR chemical shifts of the carbonyl carbons in the order of ketones > aldehydes > carboxylic acids, provide an explanation. O CH3 H3C. 13C NMR Chemical Shifts: H₂C1 H₂C H > OH 200 ppm 181 ppm 209 ppm