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- Which of the following will not act as diene reactant in a Diels Alder reaction? A) B) D) OCH3 H,CO AConsider the four trienes E–H. Which compound is most reactive in the Diels–Alder reaction?2) Rank the following dienes in order of increasing rate of Diels-Alder reaction with maleic anhydride. You do not need to explain your ranking. H3C. H3CO Diene A Diene B Diene C
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- Which diene is more reactive in a Diels–Alder reaction? CH2=CHCH=CHOCH3 or CH2=CHCH=CHCH2OCH3A2 What is the inverse electron demand Diels–Alder reaction? Please pick a pair of a diene and a dienophile from the following dienes and dienophile that will undergo this type of reaction. Please show how this reaction works using Frontier Molecular Orbitals. What is the reaction product?5. Provide structures for A and B. Explain your choices using the appropriate molecular orbital diagrams (show all MO diagrams for the dien and dienophile) for reactions under thermal-vs-photochemical conditions. Show relative stereochemistry in the products. NC NO₂ hv B H₂C CH, A A
