3. In acidsolution, chlorate(V) ions, CO, slowly oxidize chloride ions to chlorine. The following kinetic data are obtained at 25 "C. CIO1/M ICH/M 0.15 [H'1/M Initialrate/ Ms' 10x10 4.0 x 10 Experiment 008 0.20 2 0.08 0.15 0.40 3 0.16 0.15 0.40 8.0 x 10 4 0.08 0.30 0.20 20x 104 a. Write the halfequation for the axidation of chloride ion to chlorine. alan

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d. Determine the rate constant at this temperature
Transcribed Image Text:d. Determine the rate constant at this temperature
3. In acidsolution, chlorate(V) ions, CIO; slowly oxidize chloride ions to chlorine. The
following kinetic data are obtained at 25 °C.
[CH)/ M
Initialrate / Ms'
10 x 105
4.0 x 10
[CIO,1/M
[H'1/M
0.20
Experiment
0.08
0.15
2
3
0.08
0.15
0.40
0.15
0.30
8.0 x 105
2.0 x 10
0.16
0.40
0.08
0.20
a. Write the halfequation for the oxidation of chloride ion to chlorine.
b. Write the balanced equation for this reaction.
Given the half equation for reduction is:
2CIO, + 10 e + 12H → C, + H20
c. Determine the order of the reaction with respect to each rea cta nt.
Transcribed Image Text:3. In acidsolution, chlorate(V) ions, CIO; slowly oxidize chloride ions to chlorine. The following kinetic data are obtained at 25 °C. [CH)/ M Initialrate / Ms' 10 x 105 4.0 x 10 [CIO,1/M [H'1/M 0.20 Experiment 0.08 0.15 2 3 0.08 0.15 0.40 0.15 0.30 8.0 x 105 2.0 x 10 0.16 0.40 0.08 0.20 a. Write the halfequation for the oxidation of chloride ion to chlorine. b. Write the balanced equation for this reaction. Given the half equation for reduction is: 2CIO, + 10 e + 12H → C, + H20 c. Determine the order of the reaction with respect to each rea cta nt.
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