3. How could you prepare hexan-2-one from the following starting materials? (a) OH (b) CH3CH₂CH₂CH₂C=CH CH3CH₂CH₂CH₂CHCH3 CH3 CH3CH₂CH₂CH₂C=CH₂ 4. How might you prepare the following alcohols from an aldehyde or ketone? Show all possibilities. (a) (b) HO H OH CH₂CH₂OH (c) CH3 CH3 5. The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 180 is also available. When a ketone or aldehyde is dissolved in H₂O, the isotopic label becomes incorporated into the carbonyl group: R₂C=0 + H₂O → R₂C=O + H₂O. Explain. (c)
3. How could you prepare hexan-2-one from the following starting materials? (a) OH (b) CH3CH₂CH₂CH₂C=CH CH3CH₂CH₂CH₂CHCH3 CH3 CH3CH₂CH₂CH₂C=CH₂ 4. How might you prepare the following alcohols from an aldehyde or ketone? Show all possibilities. (a) (b) HO H OH CH₂CH₂OH (c) CH3 CH3 5. The oxygen in water is primarily (99.8%) 160, but water enriched with the heavy isotope 180 is also available. When a ketone or aldehyde is dissolved in H₂O, the isotopic label becomes incorporated into the carbonyl group: R₂C=0 + H₂O → R₂C=O + H₂O. Explain. (c)
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:3.
How could you prepare hexan-2-one from the following starting materials?
(a)
OH
(b) CH3CH₂CH₂CH₂C=CH
CH3CH₂CH₂CH₂CHCH3
CH3
CH3CH₂CH₂CH₂C=CH2
4.
How might you prepare the following alcohols from an aldehyde or ketone?
Show all possibilities.
(a)
H OH
(b)
CH₂CH₂OH (c)
HO CH3
CH3
5.
The oxygen in water is primarily (99.8%) 160, but water enriched with the
heavy isotope 180 is also available. When a ketone or aldehyde is dissolved in
H₂O, the isotopic label becomes incorporated into the carbonyl group: R₂C=0
+ H₂O R₂C=0 + H₂O. Explain.
(c)
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