3. Give the complete electron flow of the S1 reaction, be sure to clearly show the electrons that are flowing. Br CH,CH,CH,CH,ÓH, Bī CH-CH-CH-CH-OH
3. Give the complete electron flow of the S1 reaction, be sure to clearly show the electrons that are flowing. Br CH,CH,CH,CH,ÓH, Bī CH-CH-CH-CH-OH
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Chapter 6, 7: Understanding Reaction Mechanisms**
1. **S<sub>N</sub>2 Reaction:**
- **Reactants:** An alkoxide ion (OK⁻) and a bromoalkane.
- **Solvent:** CH₃CH₂CH₂CH₂OH (butanol).
- **Products:** Ether and potassium bromide (KBr).
- **Description:** An S<sub>N</sub>2 reaction involves a single-step nucleophilic substitution where the nucleophile (OK⁻) directly attacks the carbon atom bonded to the leaving group (Br), displacing it. Electrons flow from the nucleophile to the carbon atom.
2. **E2 Reaction:**
- **Reactants:** An alkoxide ion (OK⁻) and a bromoalkane.
- **Solvent:** CH₃CH₂CH₂CH₂OH (butanol).
- **Products:** Alkene, water, and potassium bromide (KBr).
- **Description:** An E2 reaction is a bimolecular elimination where the base (OK⁻) removes a hydrogen atom from the carbon adjacent to the one bonded to the leaving group (Br). This results in the formation of a double bond (alkene) and the release of Br⁻ as a leaving group.
3. **S<sub>N</sub>1 Reaction:**
- **Reactants:** Tertiary bromoalkane.
- **Solvent:** CH₃CH₂CH₂CH₂OH (butanol).
- **Products:** Ether and a secondary carbocation intermolecular complex with bromide.
- **Description:** An S<sub>N</sub>1 reaction involves a two-step mechanism where the leaving group (Br⁻) first dissociates, forming a carbocation intermediate. This carbocation is then attacked by the solvent (CH₃CH₂CH₂CH₂OH), leading to ether formation.
4. **E1 Reaction:**
- **Reactants:** Tertiary bromoalkane.
- **Solvent:** CH₃CH₂CH₂CH₂OH (butanol).
- **Products:** Alkene, a protonated alcohol (CH₃CH₂CH₂CH₂OH₂⁺), and bromide ion (Br⁻).
- **Description:** An E1 reaction involves a two
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