3. Express z = −1+i in polar form.
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since expression of z is given by
z = x + iy
=> x = -1 and y = 1
=>
and,
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- 7. A diatomic molecule has 2.6 x 10-5 eV of rotational energy in the L = 2 quantum state. What is the rotational energy in the L = 1 quantum state? Find the wavelength for such transition, L = 2 to L = 1.2. Hexagonal space lattice. The primitive translation vector of the hexagonal space lattice may be taken as 3a ā₂ 2 (a) Show that the volume of the primitive cell is (√3/2)a²c. (b) Show that the primitive translations of the reciprocal lattice are 2π 2π 2π 2π 2π = = ·x +· -ŷ; b₂ 3a a ·+· -ŷ; b₂ = 2, 3a a с so that the lattice is its own reciprocal, but with a rotation of axes. (c) Describe and sketch the first Brillouin zone of the hexagonal space lattice. √3a 2 b = a₁ x + 2 î+ŷ; ā=c₂. 2Quantum Mechanics, physical chemistry. Screenschot of question attached. For this question, assume the atoms have average atomic masses. Actual molecules will have different isotopes so variation in energy levels will result from different isotopes.
- p9C.1 Familiarity with the magnitudes of overlap integrals is useful when con- sidering bonding abilities of atoms, and hydrogenic orbitals give an indication of their values. (a) The overlap integral between two hydrogenic 2s orbitals is 1 ( ZR ZR +. 2а, " 12 а, 1 + ZR 240 a, -ZR/Z0 S(2s, 2s)={1+ Plot this expression. (b) For what internuclear distance is S(2s,2s) = 0.50? (c) The side-by-side overlap of two 2p orbitals of atoms of atomic number Z is ZR 1 ( ZR ZR S(2p,2p) ={1+ 10 a, 2a, 120 a. Plot this expression. (d) Evaluate S(2s,2p) at the internuclear distance you calculated in part (b).1. Using the figure below, answer the questions about the cross product ÀxČ. 60° A = 10.0 30° (a) Magnitude of Ả×č: Jà xč = X+ O X- O O +y O -y O +z (b) Direction of Axč:O -z C = 12.0The repulsive force between Na+ and Cl- ions can be written as F = Be-T/R where B = 5.45 x 10-6 N and R = 0.321 Å. At equilibrium, this force is equal to the magnitude of the attractive force given by F Determine the value of r at equilibrium. e² 4π€or²