3. Diethyl ether (molar mass 74.12 g/mol) boils at 34.6 °C and water (molar mass 18.02 g/mol) boils at 100 C. a. At 25 °C, which compound - diethyl ether or water – has the higher vapor pressure? b. Which data – molar mass or boiling point - did you use to make your choice? Explain your answer.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
The temperature at which vapour pressure of a liquid is equal to the atmospheric pressure is called boiling point. At any temperature, the vapour pressure is high implies the intermolecular forces are weak and if the vapour pressure is low suggest stronger intermolecular attraction.
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