3. By definition the pH of a dilute solution of a weak acid equals its pKa only when the concentrations of unionized acid [HA] equals the concentration of its ionized conjugate base (A 1. At any given pH an acid will be mostly ionized or unionized depending on its pKa. Given the following weak acids and their pka's decide whether the acid is mostly ionized or mostly unionized at the pH shown. la] CH,C=0)OH [pKa = 4.76] at pH = 5.76 [b] HC(=0)OH [pKa = 3.75) at pH = 2.75 [c] CH CH,CH,NH, [pKa 10.7] at pH = 8.7 fdj H,S [pKa = 7.0] at pH = 2 [el CH,OH [pKa = 15.5] at pH = 9.5

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Chapter1: Chemical Foundations
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Can you answer 3 please, its not graded, thanks
acid base reactions, draw Lewis structures for the conjugate acid and conjugate base formed when the
Immediately between acids and bases to reach an equilibrium. In the following
reactants (on the left) are mixed.
(a) CH;C(=0)OH
acetic acid
+ NH3
Acid
(conj, acid
(conj, base)
(b) HC(=0)OH
formie acd
+ CH3CH2NH2
(conj, acid
(coni. base)
(c) CH:CH2CH2C(=0)OH +Na/FOH (Na'/cr] + H2O +
butano ie acid
3. By definition the pH of a dilute solution of a weak acid equals its pka only when the concentrations of
unionized acid [HA] equals the concentration of its ionized conjugate base [A1 At any given pH an acid will be
mostly ionized or unionized depending on its pka. Given the following weak acids and their pKa's decide
whether the acid is mostly ionized or mostly unionized at the pH shown.
la] CH,C=0)OH (pKa = 4.76] at pH = 5.76
[b] HC(-0)OH
[pKa = 3.75) at pH = 2.75
(d CH CH,CH,NH, [pKa = 10.7] at pH = 8.7
fdj HS
[pka = 7.0)
at pH = 2
[e] CH,OH
IpKa = 15.5] at pH = 9.5
Transcribed Image Text:acid base reactions, draw Lewis structures for the conjugate acid and conjugate base formed when the Immediately between acids and bases to reach an equilibrium. In the following reactants (on the left) are mixed. (a) CH;C(=0)OH acetic acid + NH3 Acid (conj, acid (conj, base) (b) HC(=0)OH formie acd + CH3CH2NH2 (conj, acid (coni. base) (c) CH:CH2CH2C(=0)OH +Na/FOH (Na'/cr] + H2O + butano ie acid 3. By definition the pH of a dilute solution of a weak acid equals its pka only when the concentrations of unionized acid [HA] equals the concentration of its ionized conjugate base [A1 At any given pH an acid will be mostly ionized or unionized depending on its pka. Given the following weak acids and their pKa's decide whether the acid is mostly ionized or mostly unionized at the pH shown. la] CH,C=0)OH (pKa = 4.76] at pH = 5.76 [b] HC(-0)OH [pKa = 3.75) at pH = 2.75 (d CH CH,CH,NH, [pKa = 10.7] at pH = 8.7 fdj HS [pka = 7.0) at pH = 2 [e] CH,OH IpKa = 15.5] at pH = 9.5
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