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3. (15 points) In the Applied Organometallic Chemistry article the authors compare the relative catalytic efficiencies of the two resin-bound catalysts Pd-NHC1@M and Pd-NHC2@M in Table 1. As the mole percentage of catalyst is lowered to 0.50%, the Pd-NHC2@M catalyst is more efficient in its yield of the product of the coupling reaction shown below: Pd-NHC@M + + CO H3CO H3CO What rationale do the authors provide for the greater efficiency of Pd-NHC2@M?

3. (15 points) In the Applied Organometallic Chemistry article the authors compare the relative catalytic efficiencies of the two resin-bound catalysts Pd-NHC1@M and Pd-NHC2@M in Table 1. As the mole percentage of catalyst is lowered to 0.50%, the Pd-NHC2@M catalyst is more efficient in its yield of the product of the coupling reaction shown below: Pd-NHC@M + + CO H3CO H3CO What rationale do the authors provide for the greater efficiency of Pd-NHC2@M?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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3. (15 points) In the Applied Organometallic Chemistry article the authors compare the relative catalytic efficiencies of the two resin-bound catalysts Pd-NHC1@M and Pd-NHC2@M in Table 1. As the mole percentage of catalyst is lowered to 0.50%, the Pd-NHC2@M catalyst is more efficient in its yield of the product of the coupling reaction shown below: Pd-NHC@M + + CO H3CO H3CO What rationale do the authors provide for the greater efficiency of Pd-NHC2@M?
Transcribed Image Text:3. (15 points) In the Applied Organometallic Chemistry article the authors compare the relative catalytic efficiencies of the two resin-bound catalysts Pd-NHC1@M and Pd-NHC2@M in Table 1. As the mole percentage of catalyst is lowered to 0.50%, the Pd-NHC2@M catalyst is more efficient in its yield of the product of the coupling reaction shown below: Pd-NHC@M + + CO H3CO H3CO What rationale do the authors provide for the greater efficiency of Pd-NHC2@M?
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