3 Spectroscopy Light can be emitted and absorbed by atoms, but only when the energy of the light, E = hf, matches the energy difference of two allowed states of an atom. For the transition m→n, the energy difference is AE = Em - En. Thus, light will be emitted or absorbed only if hf = En-Em In the Bohr model of hydrogen, the energy of the n-th electron orbit is En -13.6 eV n² (a) Transitions of the form m→ 1 make up the Lyman series of spectral lines. Calculate the wavelengths of the first 3 lines in the Lyman series. In what region of the electromagnetic spectrum do these lines appear? (b) Transitions of the form m → 2 make up the Balmer series of spectral lines. Calculate the wavelengths of the first 3 lines in the Balmer series. In what region of the electromagnetic spectrum do these lines appear? (c) Transitions of the form m → 3 make up the Paschen series of spectral lines. Calculate the wavelengths of the first 3 lines in the Paschen series. In what region of the electromagnetic spectrum do these lines appear?

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3 Spectroscopy
Light can be emitted and absorbed by atoms, but only when the energy of the light, E = hf, matches the energy difference
of two allowed states of an atom. For the transition m →n, the energy difference is AE = Em - En. Thus, light will be
emitted or absorbed only if hf = En-Em-
In the Bohr model of hydrogen, the energy of the n-th electron orbit is En
-13.6 eV
n²
(a) Transitions of the form m → 1 make up the Lyman series of spectral lines. Calculate the wavelengths of the first 3
lines in the Lyman series. In what region of the electromagnetic spectrum do these lines appear?
(b) Transitions of the form m → 2 make up the Balmer series of spectral lines. Calculate the wavelengths of the first
3 lines in the Balmer series. In what region of the electromagnetic spectrum do these lines appear?
(c) Transitions of the form m → 3 make up the Paschen series of spectral lines. Calculate the wavelengths of the first
3 lines in the Paschen series. In what region of the electromagnetic spectrum do these lines appear?
Transcribed Image Text:3 Spectroscopy Light can be emitted and absorbed by atoms, but only when the energy of the light, E = hf, matches the energy difference of two allowed states of an atom. For the transition m →n, the energy difference is AE = Em - En. Thus, light will be emitted or absorbed only if hf = En-Em- In the Bohr model of hydrogen, the energy of the n-th electron orbit is En -13.6 eV n² (a) Transitions of the form m → 1 make up the Lyman series of spectral lines. Calculate the wavelengths of the first 3 lines in the Lyman series. In what region of the electromagnetic spectrum do these lines appear? (b) Transitions of the form m → 2 make up the Balmer series of spectral lines. Calculate the wavelengths of the first 3 lines in the Balmer series. In what region of the electromagnetic spectrum do these lines appear? (c) Transitions of the form m → 3 make up the Paschen series of spectral lines. Calculate the wavelengths of the first 3 lines in the Paschen series. In what region of the electromagnetic spectrum do these lines appear?
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