(3) For the following reactions at 500 K: (a) PbS(s) + 02(8)- - Pb(s) + SO2(g) (b) PbS(s) + 2P60(s) → 3Pb(s) + sO2(g) calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information: PbS(s) 0, (8) Pb(s) so, (g) PbO(s) Af0o (kJ mol-) -94 -296 -219 205 65 249 68 asic. (J K- mol") 91 In each case discuss briefly the feasibility of the reaction under the stated conditions and how the feasibility is influenced by temperature change. Calculate the reversal temperature where relevant assuming that Al and AS" remain constant over the temperature range considered.
(3) For the following reactions at 500 K: (a) PbS(s) + 02(8)- - Pb(s) + SO2(g) (b) PbS(s) + 2P60(s) → 3Pb(s) + sO2(g) calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information: PbS(s) 0, (8) Pb(s) so, (g) PbO(s) Af0o (kJ mol-) -94 -296 -219 205 65 249 68 asic. (J K- mol") 91 In each case discuss briefly the feasibility of the reaction under the stated conditions and how the feasibility is influenced by temperature change. Calculate the reversal temperature where relevant assuming that Al and AS" remain constant over the temperature range considered.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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For the following reactions at 500 K:
(a)
PbS(s) + 02(g) Pb(s) + S02(8)
(b)
PbS(s) + 2P6O(s)
→ 3Pb(s) + SO2(g)
calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information:
PbS(s)
0,(8)
Pb(s)
SO, (g)
PbO(s)
-296
-219
Afjo. (kJ mol-)
-94
AS0. (J K- mol-)
205
65
249
68
91
s00
In each case discuss briefly the feasibility of the reaction under the stated conditions
and how the feasibility is influenced by temperature change. Calculate the reversal
temperature where relevant assuming that Al and AS remain constant over the
temperature range considered.
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