(3) For the following reactions at 500 K: (a) PbS(s) + 02(8)- - Pb(s) + SO2(g) (b) PbS(s) + 2P60(s) → 3Pb(s) + sO2(g) calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information: PbS(s) 0, (8) Pb(s) so, (g) PbO(s) Af0o (kJ mol-) -94 -296 -219 205 65 249 68 asic. (J K- mol") 91 In each case discuss briefly the feasibility of the reaction under the stated conditions and how the feasibility is influenced by temperature change. Calculate the reversal temperature where relevant assuming that Al and AS" remain constant over the temperature range considered.

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Chapter1: Chemical Foundations
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(3)
For the following reactions at 500 K:
(a)
PbS(s) + 02(g) Pb(s) + S02(8)
(b)
PbS(s) + 2P6O(s)
→ 3Pb(s) + SO2(g)
calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information:
PbS(s)
0,(8)
Pb(s)
SO, (g)
PbO(s)
-296
-219
Afjo. (kJ mol-)
-94
AS0. (J K- mol-)
205
65
249
68
91
s00
In each case discuss briefly the feasibility of the reaction under the stated conditions
and how the feasibility is influenced by temperature change. Calculate the reversal
temperature where relevant assuming that Al and AS remain constant over the
temperature range considered.
Transcribed Image Text:(3) For the following reactions at 500 K: (a) PbS(s) + 02(g) Pb(s) + S02(8) (b) PbS(s) + 2P6O(s) → 3Pb(s) + SO2(g) calculate: (i) AH00, (ii) AS0, (iii) AG500, given the following information: PbS(s) 0,(8) Pb(s) SO, (g) PbO(s) -296 -219 Afjo. (kJ mol-) -94 AS0. (J K- mol-) 205 65 249 68 91 s00 In each case discuss briefly the feasibility of the reaction under the stated conditions and how the feasibility is influenced by temperature change. Calculate the reversal temperature where relevant assuming that Al and AS remain constant over the temperature range considered.
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