Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question

Transcribed Image Text:Calculate the enthalpy of reaction (AHrxn) for the following reaction:
Fe2O3(s) + 3 CO(g) → 2 Fe(s) + 3 CO2(g)
Given:
4 Fe(s) + 3 02(g) → 2 Fe203(s) AH= -1648 kJ
2 CO2(g) → 2 C0(g) + 02(g) AH = +565.4 kJ
Expert Solution

Step 1
(1) 4Fe + 3O2----> 2Fe2O3, □H = -1648 kJ
(2) 2CO2 ----> 2CO + O2, □H = +565.4 kJ
(3) Fe2O3 + 3CO ---> 2Fe + 3CO2
Using Hess's law,
Reaction (3) =
-1/2×Reaction(1) - 3/2× Reaction (2)
□H = -□H1/2 - 3□H2/2
= (1648/2) - 3 × 565.4/2
= -24.1 kJ
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