3) (7 pts) For a system composed of an aqueous solution of Cu(NO3)2 in equilibrium with water vapor and with some residual, undissolved Cu(NO3)2, indicate: (i) identify each constituent: (ii) identify each component: (iii) identify each phase present: (iv) Calculate the degrees of freedom (variance) for the system:
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- What is the free Cu2+ (ag) concentration in a solution made up by mixing 50.0 mL of 0.100M Cu(NO3)2 with 50.0 mL 1.00 M NH3 (aq)? Given: Cu2+ (ag) + 4 NH3 (aq) > < Cu(NH3)42+ (aq) K, = 1.1 x 10^13Creatinine, C4H7N3O, is a by-product of muscle metabolism, and creatinine levels in the body are known to be a fairly reliable indicator of kidney function. The normal level of creatinine in the blood for adults is approximately 1.0 mg per deciliter (dL) of blood. If the density of blood is 1.025 g/mL, calculate the molarity of a normal creatinine level in a 10.0 mL blood sample.What is the chemistry principle behind when (treatment: heavy cream) is subjected to room temperature? Why does beating time, stability (%drain) and volume foam (specific gravity) is important? see the data below Treatment (Heavy Cream) Beating Time (min) Stability (%drain) Volume of Foam (Specific Gravity) (Room Temperature) 20 No drain 0.94 Heavy Cream (chilled) 20 No drain 0.76 Heavy Cream with sugar and vanilla 20 No drain 0.88 Heavy Cream (over-whipped) 25 No drain 0.83
- The amount of calcium in physiologic fluids can be determined by a complexometric titration with EDTA. In one such analysis, a 0.100-mL sample of blood serum was made basic by adding 2 drops of NaOH and titrated with 0.001 M EDTA, requiring 0.238 mL to reach the end point. Report the concentration of calcium in the sample as miligrams of Ca per 100 mL. (Ca = 40.078 amu).Using the formula V₁D₁ = V₂D2, what volume of a 1/100 (10-2) dilution would you need to produce 100 mL of a 1/10000 (10-4) dilution? (Note: provide your answer in decimal format to three decimal places.)To make up a solution of phosphate buffered saline (PBS), you need 10 mM Na2HPO4 (anhydrous) (FW: 141.96 g/mol), 3 M NaCl (FW: 58.44 g/mol), and 5mM KH2PO4 (FW: 136.09 g/mol). How many grams of each will you need to make up 850 mL of PBS?
- After three minutes, the concentration of drug Zip in the red blood cells is 10 mmoles l-1. What is the average rate of entry of drug Zip into the red blood cells in units of moles min-1 red blood cell-1 during the first three minutes after placing the red blood cells into the bathing solution? Assume that each red blood cell occupies about 1 x 10-13 liters.Consider the titration of 30.0 mL of 0.0700 M HONH2 (a weak base; Kb = 1.10e-08) with 0.100 M HI. Calculate the pH after the following volumes of titrant have been added: (a) 0.0 mLpH = (b) 5.3 mLpH = (c) 10.5 mLpH = (d) 15.8 mLpH = (e) 21.0 mLpH = (f) 27.3 mLpH =The normal freezing point of benzene (C6H6) is 5.5 °C. If 30.92 grams of the nonvolatile nonelectrolyte diphenylether (C12H100), are dissolved in 212.1 grams of benzene, what is the freezing point of the resulting solution? Kfp for benzene is 5.12 °C/m. °C
- Determine the weight/volume of the chemicals needed to prepare the following solutions: a) 100 ml of 0.9% (w/v) saline (NaCl) b) 30 ml of 50% glycerol (v/v) c) Electrophoresis requires TAE, which is a specific mixture of Tris base, acetic acid, and EDTA. TAE is normally made as a 50X concentrated stock. Provide a recipe to make 40 ml of 50X TAE. The recipe for one liter of 50X TAE is as follows: 242g Tris base, 57.1 ml glacial acetic acid, 100 ml 0.5 M EDTAThe main constituents in vinegar are water and ethanoic acid (CH3COOH). In order to determine the concentration of acid in homemade vinegar, a student titrated 25 cm3 of 001 M NaOH against the vinegar. The equation for the reaction is: CH3COOH(aq) + NaOH(aq) ® CH3COONa(aq) + H2O(l) The following titration results were obtained: Burette readings (cm3) Rough 1 2 Final burette reading 20.10 38.90 31.40 Initial burette reading 0.10 20.00 12.50 Volume of vinegar used 20.00 18.90 18.90 (a) What volume of vinegar should be used in the calculation? (b) What is the mole ratio of NaOH:CH3COOH? (c) Calculate the number of moles of alkali in 25 cm3 of NaOH solution used. (d) How many moles of acid were used in the titration? (e) Calculate the…How many moles of EDTA (C10H16N2O3) do you have in 785µl of a 74MM EDTA solution (Mr(C10H16N203) = 292.24)? Consider all digits of your Givens significant. Round results to the appropriate number of Significant Digits. The number of moles is mmol.