25° C for the formation of the ions [M(en)(H,O)4]²*, [M(en)2(H2O)2]?+, and [M(en);]2+ for copper and nickel are given in the table. Why is there such a difference in the third values? (Hint: Consider the special nature of d complexes.) 12+ [M(en);]2+ 0.1 (estimated) [M(en)(H,O),1²+ [M(en),(H,0),1²+ Cu 3 X 1010 1 × 10° Ni 2 × 107 1 × 106 1 × 104

25° C for the formation of the ions [M(en)(H,O)4]²*, [M(en)2(H2O)2]?+, and [M(en);]2+ for copper and nickel are given in the table. Why is there such a difference in the third values? (Hint: Consider the special nature of d complexes.) 12+ [M(en);]2+ 0.1 (estimated) [M(en)(H,O),1²+ [M(en),(H,0),1²+ Cu 3 X 1010 1 × 10° Ni 2 × 107 1 × 106 1 × 104

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Which of the following order is true with respect to the color/electronic spectra of[Fe(H2O)6]3+, KMnO4, [NiCl4]2-?(a) εKMnO4 > ε [Fe(H2O)6]3+ > ε [Ni(Cl)4]2-(b) ε KMnO4 > ε [Ni(Cl)4]2- > ε [Fe(H2O)6]3+(c) ε [Ni(Cl)4]2- > ε [Fe(H2O)6]3+ > εKMnO4(d) ε [Fe(H2O)6]3+ > ε [Ni(Cl)4]2- > εKMnO4
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