23. Tertiary butyl chloride undergoes substitution by hydroxide ion according to the equation below. (CH3)3CCI- + OH → (CH3)3COH + Cl Experimental evidence showed that the reaction obeys the rate law, Rate = k [(CH3)3CCI]. Which of the following mechanisms is consistent with the observed rate law? Step 1 -(CH3)3CCI+ OH → (CH3)3C + HOCI Slow a. Step 2-(CH3)3C + HOCI (CH3)3COH + CI Fast b. Step 1 -(CH3)3CCI→ (CH3)3C + Cl Slow Step 2 -(CH3)3C + OH (CH3)3COH Fast c. (CH3)3CCI + OH → (CH3)3COH + Cl d. Step 1 -(CH3)3CCI → (CH3)3C + Cl Fast Step 2-OH → H+0² Slow e. Step 3 -(CH3)3C+0²+H(CH3)3COH Fast Step 1 -(CH3)3CCI + OH (CH3)3C + HOCI Fast Step 2 -(CH3)3C + HOCI → (CH3)3COH + CI Slow

23. Tertiary butyl chloride undergoes substitution by hydroxide ion according to the equation below. (CH3)3CCI- + OH → (CH3)3COH + Cl Experimental evidence showed that the reaction obeys the rate law, Rate = k [(CH3)3CCI]. Which of the following mechanisms is consistent with the observed rate law? Step 1 -(CH3)3CCI+ OH → (CH3)3C + HOCI Slow a. Step 2-(CH3)3C + HOCI (CH3)3COH + CI Fast b. Step 1 -(CH3)3CCI→ (CH3)3C + Cl Slow Step 2 -(CH3)3C + OH (CH3)3COH Fast c. (CH3)3CCI + OH → (CH3)3COH + Cl d. Step 1 -(CH3)3CCI → (CH3)3C + Cl Fast Step 2-OH → H+0² Slow e. Step 3 -(CH3)3C+0²+H(CH3)3COH Fast Step 1 -(CH3)3CCI + OH (CH3)3C + HOCI Fast Step 2 -(CH3)3C + HOCI → (CH3)3COH + CI Slow

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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