22. Muscarine is the poisonous component in poison mushrooms. (-)-Menthol is a common ingredient in commercial compounds due to its fragrance. a) Indicate the number of possible stereoisomers for each structure. The configuration of biologically active muscarine is 2S,3R,5S. Draw wedge-dash diagram on the structure of muscarine below, showing the absolute stereochemistry. For (-)-menthol assign each stereocenter R/S configuration. b) Name Muscarine (-)-Menthol H3C H3C OH- -N-CH3 CH3 Structure H3C- но "OH H3C `CH3 Number of stereoisomers possible
22. Muscarine is the poisonous component in poison mushrooms. (-)-Menthol is a common ingredient in commercial compounds due to its fragrance. a) Indicate the number of possible stereoisomers for each structure. The configuration of biologically active muscarine is 2S,3R,5S. Draw wedge-dash diagram on the structure of muscarine below, showing the absolute stereochemistry. For (-)-menthol assign each stereocenter R/S configuration. b) Name Muscarine (-)-Menthol H3C H3C OH- -N-CH3 CH3 Structure H3C- но "OH H3C `CH3 Number of stereoisomers possible
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:22. Muscarine is the poisonous component in poison mushrooms. (-)-Menthol is a common
ingredient in commercial compounds due to its fragrance.
a)
Indicate the number of possible stereoisomers for each structure.
The configuration of biologically active muscarine is 2S,3R,5S. Draw
wedge-dash diagram on the structure of muscarine below, showing the
absolute stereochemistry.
For (-)-menthol assign each stereocenter R/S configuration.
b)
Name
Muscarine
(-)-Menthol
H3C
H3C OH-
-N-CH3
CH3
Structure
H3C-
но
"OH
H3C
`CH3
Number of
stereoisomers
possible
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