"2.36. The following reactions take place in a batch reactor: A +B → C (desired product) B+ C → D (hazardous product) As the reaction proceeds, D builds up in the reactor and could cause an explosion if its concentration exceeds 15 mol/L. To ensure the safety of the plant personnel, the reaction is quenched (e.g., by cooling the reactor contents to a low temperature) and the products are extracted when the concentration of D reaches 10 mol/L. The concentration of C is measured in real-time, and samples are periodically taken and analyzed to determine the concentration of D. The data are shown below: Cc (mol/L) Cp (mol/L) 2.8 1.4 10 2.27 20 2.95 40 3.84 70 4.74 110 5.63 160 6.49 220 7.32 a. What would be the general form of an expression for Cp as a function of Cc? b. Derive the expression. c. At what concentration of C is the reactor stopped? Answer d. Someone proposed not stopping the reaction until Cp = 13 mol/L, and someone else strongly objected. What would be the major arguments for and against that proposal? 2.37. WP The vapor pressures of 1-chlorotetradecane at several temperatures are tabulated here. T(°C) 98.5 131.8 148.2 166.2 199.8 215.5 p* (mm Hg) 5 10 20 б0 100 a. Use two-point linear interpolation to estimate the value of p* at T = 185°C. b. Suppose you only know the data at 98.5°C and 215.5°C. Use two-point linear interpolation to estimate the vapor pressure at

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
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"2.36. The following reactions take place in a batch reactor:
A +B → C (desired product)
B+ C → D (hazardous product)
As the reaction proceeds, D builds up in the reactor and could cause an explosion if its concentration exceeds 15 mol/L. To ensure
the safety of the plant personnel, the reaction is quenched (e.g., by cooling the reactor contents to a low temperature) and the
products are extracted when the concentration of D reaches 10 mol/L.
The concentration of C is measured in real-time, and samples are periodically taken and analyzed to determine the concentration
of D. The data are shown below:
Cc (mol/L) Cp (mol/L)
2.8
1.4
10
2.27
20
2.95
40
3.84
70
4.74
110
5.63
160
6.49
220
7.32
a. What would be the general form of an expression for Cp as a function of Cc?
b. Derive the expression.
c. At what concentration of C is the reactor stopped?
Answer
d. Someone proposed not stopping the reaction until Cp = 13 mol/L, and someone else strongly objected. What would be the
major arguments for and against that proposal?
2.37. WP The vapor pressures of 1-chlorotetradecane at several temperatures are tabulated here.
T(°C)
98.5 131.8 148.2 166.2 199.8 215.5
p* (mm Hg)
5
10
20
б0
100
a. Use two-point linear interpolation to estimate the value of p* at T = 185°C.
b. Suppose you only know the data at 98.5°C and 215.5°C. Use two-point linear interpolation to estimate the vapor pressure at
Transcribed Image Text:"2.36. The following reactions take place in a batch reactor: A +B → C (desired product) B+ C → D (hazardous product) As the reaction proceeds, D builds up in the reactor and could cause an explosion if its concentration exceeds 15 mol/L. To ensure the safety of the plant personnel, the reaction is quenched (e.g., by cooling the reactor contents to a low temperature) and the products are extracted when the concentration of D reaches 10 mol/L. The concentration of C is measured in real-time, and samples are periodically taken and analyzed to determine the concentration of D. The data are shown below: Cc (mol/L) Cp (mol/L) 2.8 1.4 10 2.27 20 2.95 40 3.84 70 4.74 110 5.63 160 6.49 220 7.32 a. What would be the general form of an expression for Cp as a function of Cc? b. Derive the expression. c. At what concentration of C is the reactor stopped? Answer d. Someone proposed not stopping the reaction until Cp = 13 mol/L, and someone else strongly objected. What would be the major arguments for and against that proposal? 2.37. WP The vapor pressures of 1-chlorotetradecane at several temperatures are tabulated here. T(°C) 98.5 131.8 148.2 166.2 199.8 215.5 p* (mm Hg) 5 10 20 б0 100 a. Use two-point linear interpolation to estimate the value of p* at T = 185°C. b. Suppose you only know the data at 98.5°C and 215.5°C. Use two-point linear interpolation to estimate the vapor pressure at
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