H =0 H 0: R HN AN H R 0 2 the H 0-04 + R HN N R R HN N -R -O-OH H 0 H 2 1 2. Tryptophan in a peptide chain is a major target of singlet oxygen. Please provide two possible products of the reaction of '02 with tryptophan and a mechanism for their formation. Note that the benzene ring is unreactive. R -NH ΙΖ R 102 Two products N H Tryptophan in a peptide

Biochemistry
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ISBN:9781319114671
Author:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Publisher:Lubert Stryer, Jeremy M. Berg, John L. Tymoczko, Gregory J. Gatto Jr.
Chapter1: Biochemistry: An Evolving Science
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H
=0
H
0:
R HN
AN
H
R
0
2
the
H
0-04
+
R
HN
N
R
R
HN
N
-R
-O-OH
H
0
H
2
1
Transcribed Image Text:H =0 H 0: R HN AN H R 0 2 the H 0-04 + R HN N R R HN N -R -O-OH H 0 H 2 1
2. Tryptophan in a peptide chain is a major target of singlet oxygen. Please provide two
possible products of the reaction of '02 with tryptophan and a mechanism for their
formation. Note that the benzene ring is unreactive.
R
-NH
ΙΖ
R
102
Two products
N
H
Tryptophan in a peptide
Transcribed Image Text:2. Tryptophan in a peptide chain is a major target of singlet oxygen. Please provide two possible products of the reaction of '02 with tryptophan and a mechanism for their formation. Note that the benzene ring is unreactive. R -NH ΙΖ R 102 Two products N H Tryptophan in a peptide
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