2. Please calculate the standard enthalpy of reaction (AHxn, in kJ/mol) for the preparation of nitrous acid, HNO2, using the thermodynamic data given below. Preparation of nitrous acid: HCl(g) + NaNO2(s)→ HNO2(1) + NaCl(s) 2NaCl(s) + H₂O(l) → 2HCl(g) + Na₂O(s) NO(g) + NO₂(g) + Na₂O(s) → 2NaNO₂(s) NO(g) + NO2(g) → N₂O(g) + O₂(g) 2HNO2(1)→ N₂O(g) + O₂(g) + H₂O(g) H₂O(1)→ H₂O(g) ΔΗ 507.31 kJ/mol AH-427.14 kJ/mol AH = -42.68 kJ/mol ΔΗ = 34.35 kJ/mol ΔΗ 44.012 kJ/mol
2. Please calculate the standard enthalpy of reaction (AHxn, in kJ/mol) for the preparation of nitrous acid, HNO2, using the thermodynamic data given below. Preparation of nitrous acid: HCl(g) + NaNO2(s)→ HNO2(1) + NaCl(s) 2NaCl(s) + H₂O(l) → 2HCl(g) + Na₂O(s) NO(g) + NO₂(g) + Na₂O(s) → 2NaNO₂(s) NO(g) + NO2(g) → N₂O(g) + O₂(g) 2HNO2(1)→ N₂O(g) + O₂(g) + H₂O(g) H₂O(1)→ H₂O(g) ΔΗ 507.31 kJ/mol AH-427.14 kJ/mol AH = -42.68 kJ/mol ΔΗ = 34.35 kJ/mol ΔΗ 44.012 kJ/mol
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![### Calculation of the Standard Enthalpy of Reaction (\(\Delta H_{\text{rxn}}\)) for the Preparation of Nitrous Acid, HNO\(_2\)
To calculate the standard enthalpy of reaction (\(\Delta H_{\text{rxn}}\), in kJ/mol) for producing nitrous acid, using the given thermodynamic data:
**Reaction for Preparation of Nitrous Acid:**
\[ \text{HCl(g)} + \text{NaNO}_2(\text{s}) \rightarrow \text{HNO}_2(\text{l}) + \text{NaCl(s)} \]
**Thermodynamic Reactions and Enthalpy Changes (\(\Delta H\)):**
1. **\[ 2\text{NaCl(s)} + \text{H}_2\text{O(l)} \rightarrow 2\text{HCl(g)} + \text{Na}_2\text{O(s)} \]**
- \(\Delta H = 507.31 \, \text{kJ/mol}\)
2. **\[ \text{NO(g)} + \text{NO}_2\text{(g)} + \text{Na}_2\text{O(s)} \rightarrow 2\text{NaNO}_2(\text{s)} \]**
- \(\Delta H = -427.14 \, \text{kJ/mol}\)
3. **\[ \text{NO(g)} + \text{NO}_2\text{(g)} \rightarrow \text{N}_2\text{O(g)} + \text{O}_2(\text{g)} \]**
- \(\Delta H = -42.68 \, \text{kJ/mol}\)
4. **\[ 2\text{HNO}_2\text{(l)} \rightarrow \text{N}_2\text{O(g)} + \text{O}_2(\text{g)} + \text{H}_2\text{O(g)} \]**
- \(\Delta H = 34.35 \, \text{kJ/mol}\)
5. **\[ \text{H}_2\text{O(l)} \rightarrow \text{H}_2\text{O(g)} \]**
- \(\Delta H = 44.012 \, \text{kJ/mol}\)
Each](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fef179162-973e-41f0-bb3a-1bfb38a065ce%2Fead41cba-1b0e-4ca9-987e-971b265637be%2Fr91far_processed.png&w=3840&q=75)
Transcribed Image Text:### Calculation of the Standard Enthalpy of Reaction (\(\Delta H_{\text{rxn}}\)) for the Preparation of Nitrous Acid, HNO\(_2\)
To calculate the standard enthalpy of reaction (\(\Delta H_{\text{rxn}}\), in kJ/mol) for producing nitrous acid, using the given thermodynamic data:
**Reaction for Preparation of Nitrous Acid:**
\[ \text{HCl(g)} + \text{NaNO}_2(\text{s}) \rightarrow \text{HNO}_2(\text{l}) + \text{NaCl(s)} \]
**Thermodynamic Reactions and Enthalpy Changes (\(\Delta H\)):**
1. **\[ 2\text{NaCl(s)} + \text{H}_2\text{O(l)} \rightarrow 2\text{HCl(g)} + \text{Na}_2\text{O(s)} \]**
- \(\Delta H = 507.31 \, \text{kJ/mol}\)
2. **\[ \text{NO(g)} + \text{NO}_2\text{(g)} + \text{Na}_2\text{O(s)} \rightarrow 2\text{NaNO}_2(\text{s)} \]**
- \(\Delta H = -427.14 \, \text{kJ/mol}\)
3. **\[ \text{NO(g)} + \text{NO}_2\text{(g)} \rightarrow \text{N}_2\text{O(g)} + \text{O}_2(\text{g)} \]**
- \(\Delta H = -42.68 \, \text{kJ/mol}\)
4. **\[ 2\text{HNO}_2\text{(l)} \rightarrow \text{N}_2\text{O(g)} + \text{O}_2(\text{g)} + \text{H}_2\text{O(g)} \]**
- \(\Delta H = 34.35 \, \text{kJ/mol}\)
5. **\[ \text{H}_2\text{O(l)} \rightarrow \text{H}_2\text{O(g)} \]**
- \(\Delta H = 44.012 \, \text{kJ/mol}\)
Each
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