2. In a halogenation reaction, a radical intermediate is formed at a saturated carbon. Draw all possible radical intermediates for the reaction shown. Br2 hv a) Label all saturated carbons in the starting material as 1°, 2° or 3° as appropriate. Rank these intermediates by stability. b) Since bromination occurs exclusively through the most stable intermediate, draw the monobrominated product for this reaction. c) Draw the monochlorinated products obtained if a chlorination was performed instead of a bromination.
2. In a halogenation reaction, a radical intermediate is formed at a saturated carbon. Draw all possible radical intermediates for the reaction shown. Br2 hv a) Label all saturated carbons in the starting material as 1°, 2° or 3° as appropriate. Rank these intermediates by stability. b) Since bromination occurs exclusively through the most stable intermediate, draw the monobrominated product for this reaction. c) Draw the monochlorinated products obtained if a chlorination was performed instead of a bromination.
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Transcribed Image Text:In a halogenation reaction, a radical intermediate is formed at a saturated carbon. Draw all possible radical intermediates for the reaction shown.
**Chemical Reaction:**
A molecular structure is shown on the left with a benzene ring attached to a three-carbon chain. The reaction conditions are indicated with Br₂ and hv (light) above an arrow pointing to the right.
a) Label all saturated carbons in the starting material as 1°, 2°, or 3° as appropriate. Rank these intermediates by stability.
b) Since bromination occurs exclusively through the most stable intermediate, draw the monobrominated product for this reaction.
c) Draw the monochlorinated products obtained if a chlorination was performed instead of a bromination.
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