2. Give the IUPAC name for the molecule CH3CH2CH(C2H5)CH(CH;)CH3. 3. Write the mechanism for the preparation of 1, 1- dichloroethane from ethylene. 4. Monochlorodecane (C10H21CI) is used in the preparation of surfactants though not available to any appreciable extent in natural products. a. Write two reaction paths for the production of monochlorodecane (CıoH21CI) by reaction of i. Decane (C10H22) with molecular chlorine (Cl2). Decene (C10H20) with hydrogen chloride (HC). b. What type of reaction occurs in both (i) and (ii) above? ii. 5. A moth repellent, para-dichlorobenzene, has the composition 49.1 % C, 2.7 % H and 48.2 % Cl. i. Determine the empirical formula of the compound. ii. If the molecular weight of the repellent is 147 amu, what is the molecular formula? 6. 2,3 – dimethyl – 2- butanol is subjected to acid catalyzed dehydration and yields a mixture of two isomeric alkanes. i. Draw the bond line structure for this compound. Identify the two alkenes Which one is the major product on the basis of the Zaitsev rule? ii. iii.
2. Give the IUPAC name for the molecule CH3CH2CH(C2H5)CH(CH;)CH3. 3. Write the mechanism for the preparation of 1, 1- dichloroethane from ethylene. 4. Monochlorodecane (C10H21CI) is used in the preparation of surfactants though not available to any appreciable extent in natural products. a. Write two reaction paths for the production of monochlorodecane (CıoH21CI) by reaction of i. Decane (C10H22) with molecular chlorine (Cl2). Decene (C10H20) with hydrogen chloride (HC). b. What type of reaction occurs in both (i) and (ii) above? ii. 5. A moth repellent, para-dichlorobenzene, has the composition 49.1 % C, 2.7 % H and 48.2 % Cl. i. Determine the empirical formula of the compound. ii. If the molecular weight of the repellent is 147 amu, what is the molecular formula? 6. 2,3 – dimethyl – 2- butanol is subjected to acid catalyzed dehydration and yields a mixture of two isomeric alkanes. i. Draw the bond line structure for this compound. Identify the two alkenes Which one is the major product on the basis of the Zaitsev rule? ii. iii.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:2. Give the IUPAC name for the molecule CH3CH2CH(C2H5)CH(CH;)CH3.
3. Write the mechanism for the preparation of 1, 1- dichloroethane from ethylene.
4. Monochlorodecane (C10H21CI) is used in the preparation of surfactants though not available to
any appreciable extent in natural products.
a. Write two reaction paths for the production of monochlorodecane (CıoH21CI) by reaction of
i.
Decane (C10H22) with molecular chlorine (Cl2).
Decene (C10H20) with hydrogen chloride (HC).
b. What type of reaction occurs in both (i) and (ii) above?
ii.
5. A moth repellent, para-dichlorobenzene, has the composition 49.1 % C, 2.7 % H and 48.2 % Cl.
i.
Determine the empirical formula of the compound.
ii.
If the molecular weight of the repellent is 147 amu, what is the molecular formula?
6. 2,3 – dimethyl – 2- butanol is subjected to acid catalyzed dehydration and yields a mixture of
two isomeric alkanes.
i.
Draw the bond line structure for this compound.
Identify the two alkenes
Which one is the major product on the basis of the Zaitsev rule?
ii.
iii.
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