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2. Consider a particular substance. The isothermal compressibility and coefficient of thermal expansion are given by: T2 K = C1 VP2 T a = C3 VP T + C2 VP3 1 + C4 VP2 With C1 Рa-m3 C2 = Pa2-m3 = 2.0 Ра-m3 ,and c4 K2 Pa2-m3 = 1.0 = 0.5 , C3 = 1.0 K2 K K 2a. Determine an exact differential for dV using these two equations. Demonstrate that this exact differential does indeed satisfy the Maxwell relations.

2. Consider a particular substance. The isothermal compressibility and coefficient of thermal expansion are given by: T2 K = C1 VP2 T a = C3 VP T + C2 VP3 1 + C4 VP2 With C1 Рa-m3 C2 = Pa2-m3 = 2.0 Ра-m3 ,and c4 K2 Pa2-m3 = 1.0 = 0.5 , C3 = 1.0 K2 K K 2a. Determine an exact differential for dV using these two equations. Demonstrate that this exact differential does indeed satisfy the Maxwell relations.

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. Consider a particular substance. The isothermal compressibility and coefficient of thermal expansion are given by: T2 K = C1 VP2 T a = C3° VP T + C2 VP3 1 + C4 VP2 Pa-m3 C2 = 2.0 Pa2-m3 , C3 Pa-m3 1.0 Pa2-m3 With c, = 0.5 K2 and c4 = 1.0 K K K2 2a. Determine an exact differential for dV using these two equations. Demonstrate that this exact differential does indeed satisfy the Maxwell relations.
Transcribed Image Text:2. Consider a particular substance. The isothermal compressibility and coefficient of thermal expansion are given by: T2 K = C1 VP2 T a = C3° VP T + C2 VP3 1 + C4 VP2 Pa-m3 C2 = 2.0 Pa2-m3 , C3 Pa-m3 1.0 Pa2-m3 With c, = 0.5 K2 and c4 = 1.0 K K K2 2a. Determine an exact differential for dV using these two equations. Demonstrate that this exact differential does indeed satisfy the Maxwell relations.
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