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2. Consider 1,3-cyclobutadiene, and answer the following: a) To what point group does it belong?

2. Consider 1,3-cyclobutadiene, and answer the following: a) To what point group does it belong?

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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2. Consider 1,3-cyclobutadiene, and answer the following: a) To what point group does it belong? b) The T-bonding electron system is a result of the overlap of the p, orbitals on the four carbons. Find the irreducible representations spanned by this basis set and construct the symmetry adapted linear combinations of these four orbitals. Order them from lowest to highest energy. HINT: Lowest energy combination will change sign the least (e.g. pi+p2+p3+p4 does not change sign at all).
Transcribed Image Text:2. Consider 1,3-cyclobutadiene, and answer the following: a) To what point group does it belong? b) The T-bonding electron system is a result of the overlap of the p, orbitals on the four carbons. Find the irreducible representations spanned by this basis set and construct the symmetry adapted linear combinations of these four orbitals. Order them from lowest to highest energy. HINT: Lowest energy combination will change sign the least (e.g. pi+p2+p3+p4 does not change sign at all).
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