2 molecules of A come together to form an AA dimer. The rate of binding is slightly less than diffusion controlled with a rate constant of 2 x 106 M-¹ s-¹. The rate at which the complex dissociates is 0.1 s-¹. (a) Calculate Kp for this reaction. (b) Assuming that you start with 1 mM A, calculate the first two half-lives for the reaction. In this latter calculation, assume that the rate of dissociation is 0.
2 molecules of A come together to form an AA dimer. The rate of binding is slightly less than diffusion controlled with a rate constant of 2 x 106 M-¹ s-¹. The rate at which the complex dissociates is 0.1 s-¹. (a) Calculate Kp for this reaction. (b) Assuming that you start with 1 mM A, calculate the first two half-lives for the reaction. In this latter calculation, assume that the rate of dissociation is 0.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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You are studying a binding reaction where 2 molecules of A come together to form an AA dimer. The rate of binding is slightly less than diffusion controlled with a rate constant of 2 x 106 M-¹ s-¹. The rate at which the complex dissociates is 0.1 s-¹. (a) Calculate Kp for this reaction. (b) Assuming that you start with 1 mM A, calculate the first two half-lives for the reaction. In this latter calculation, assume that the rate of dissociation is 0.
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