2 Mature crocodiles secrete from their skin glands the compound with the following structure. This compound is thought to be a communication pheromone for nesting or mating.
2 Mature crocodiles secrete from their skin glands the compound with the following structure. This compound is thought to be a communication pheromone for nesting or mating.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question
![5.52 Mature crocodiles secrete from their skin glands the compound with the
following structure. This compound is thought to be a communication
pheromone for nesting or mating.
a. How many stereogenic centers are there in this compound? Mark them with an asterisk.
b. Two stereoisomers of this compound have been isolated from crocodile skin gland secretions. How many
possible stereoisomers of this compound are there?
Additional Questions:
5bb
(1) Which compound is the diastereomer of the following compound?
H3C
CH3
Br
F
H
H3C
CH
H3C
CH3
H3C
CH3
H,C
CH3
H
F
H"
H
Br
"Br
F
F
Br
H.
Br
H
H
A
(2) Which compound is the mesomer of the following compound?
H;C
CH3
CH3
H3C
H
F
H3C
CH,
CH3
H E
H""H
H
Br
F
H
A
B
D](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1ba4d575-1d63-48c4-b5c1-5d5dd8d8cc78%2F7e8cef9b-0f97-4db4-813d-f402f9e66d03%2F4ka2gzd_processed.jpeg&w=3840&q=75)
Transcribed Image Text:5.52 Mature crocodiles secrete from their skin glands the compound with the
following structure. This compound is thought to be a communication
pheromone for nesting or mating.
a. How many stereogenic centers are there in this compound? Mark them with an asterisk.
b. Two stereoisomers of this compound have been isolated from crocodile skin gland secretions. How many
possible stereoisomers of this compound are there?
Additional Questions:
5bb
(1) Which compound is the diastereomer of the following compound?
H3C
CH3
Br
F
H
H3C
CH
H3C
CH3
H3C
CH3
H,C
CH3
H
F
H"
H
Br
"Br
F
F
Br
H.
Br
H
H
A
(2) Which compound is the mesomer of the following compound?
H;C
CH3
CH3
H3C
H
F
H3C
CH,
CH3
H E
H""H
H
Br
F
H
A
B
D
![Homework 13 Answers
5.42 How many stereoisomers are possible for each of the following structures? Draw them. and name each by the R-S
and E-Z conventions, (See Problem 5.41.)
a. 2,5-dichloro-3-hexene
c. 3-methyl-1,4-pentadiene
b. 2-chloro-5-fluoro-3-hexene
d. 3-methyl-1,4-heptadiene
5.44 Following are Newman projections for the three tartaric acids (R.R), (S,S), and meso. Which is which?
CO.H
CO,H
CO.H
H.
H.
HO
HO
Но
H.
H
HO
CO.H
CO,H
CO,H
5.49 Chloramphenicol is an antibiotic that is particularly effective against typhoid fever. Its structure is
NO,
HO
-NHCOCHCI,
CH,OH
What is the configuration (R.S) at each stereogenic center?
5.50 Methoprene (marketed as Precor), an insect juvenile hormone mimic used in
flea control products for pets, works by preventing the development of flea eggs
and larvae. The effective form of methoprene, shown here, is optically active.
Locate the stereogenic center and determine its configuration (R,S).
H,C CH, H,C H
CH,O
methoprene](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F1ba4d575-1d63-48c4-b5c1-5d5dd8d8cc78%2F7e8cef9b-0f97-4db4-813d-f402f9e66d03%2Fydjy8mb_processed.jpeg&w=3840&q=75)
Transcribed Image Text:Homework 13 Answers
5.42 How many stereoisomers are possible for each of the following structures? Draw them. and name each by the R-S
and E-Z conventions, (See Problem 5.41.)
a. 2,5-dichloro-3-hexene
c. 3-methyl-1,4-pentadiene
b. 2-chloro-5-fluoro-3-hexene
d. 3-methyl-1,4-heptadiene
5.44 Following are Newman projections for the three tartaric acids (R.R), (S,S), and meso. Which is which?
CO.H
CO,H
CO.H
H.
H.
HO
HO
Но
H.
H
HO
CO.H
CO,H
CO,H
5.49 Chloramphenicol is an antibiotic that is particularly effective against typhoid fever. Its structure is
NO,
HO
-NHCOCHCI,
CH,OH
What is the configuration (R.S) at each stereogenic center?
5.50 Methoprene (marketed as Precor), an insect juvenile hormone mimic used in
flea control products for pets, works by preventing the development of flea eggs
and larvae. The effective form of methoprene, shown here, is optically active.
Locate the stereogenic center and determine its configuration (R,S).
H,C CH, H,C H
CH,O
methoprene
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