1E.11 Magnesium ions form complexes with both ATP and ADP. The standard enthalpy of reaction for the hydrolysis of ATP to ADP and inorganic phosphate (PO3, which is denoted Pi) has been measured at pH = 7 and 25 °C for two different concentrations of magnesium ions: [Mg2+(aq)]/(mmol dm³) 0 1.0 Ahydrolysis He/(kJ mol¯¹) -21.7 -25.1 The standard reaction enthalpy for the formation of the complex between Mg 2+ and ADP is +18.0 kJ mol¯1. Calculate the standard reaction enthalpy for the formation of the complex between Mg2+ and ATP. Why does the presence of magnesium ions affect the reaction enthalpy for the hydrolysis of ATP?

University Physics Volume 2
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Chapter2: The Kinetic Theory Of Gases
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Problem 54P: (a) Using data from the previous problem, find the mass of nitrogen, oxygen, and argon in 1 mol of...
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1E.11
Magnesium ions form complexes with both ATP and ADP. The standard enthalpy of reaction for the hydrolysis of
ATP to ADP and inorganic phosphate (PO3, which is denoted Pi) has been measured at pH = 7 and 25 °C for
two different concentrations of magnesium ions:
[Mg2+(aq)]/(mmol dm³)
0
1.0
Ahydrolysis He/(kJ mol¯¹)
-21.7
-25.1
The standard reaction enthalpy for the formation of the complex between Mg 2+ and ADP is +18.0 kJ mol¯1. Calculate the
standard reaction enthalpy for the formation of the complex between Mg2+ and ATP. Why does the presence of magnesium
ions affect the reaction enthalpy for the hydrolysis of ATP?
Transcribed Image Text:1E.11 Magnesium ions form complexes with both ATP and ADP. The standard enthalpy of reaction for the hydrolysis of ATP to ADP and inorganic phosphate (PO3, which is denoted Pi) has been measured at pH = 7 and 25 °C for two different concentrations of magnesium ions: [Mg2+(aq)]/(mmol dm³) 0 1.0 Ahydrolysis He/(kJ mol¯¹) -21.7 -25.1 The standard reaction enthalpy for the formation of the complex between Mg 2+ and ADP is +18.0 kJ mol¯1. Calculate the standard reaction enthalpy for the formation of the complex between Mg2+ and ATP. Why does the presence of magnesium ions affect the reaction enthalpy for the hydrolysis of ATP?
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