19.39) For each of the following pairs, predict which substance has the higher entropy per mole at a given temperature: (a) I2(s) or I2(8) (b) O2(8) at 50.7 kPa or O2 at 101.3 kPa (c) 1 mol of N, in 22.4Lor1 mol of N2 in 44.8 L. (d) CH;OH(I) or CH3ОH (s).
19.39) For each of the following pairs, predict which substance has the higher entropy per mole at a given temperature: (a) I2(s) or I2(8) (b) O2(8) at 50.7 kPa or O2 at 101.3 kPa (c) 1 mol of N, in 22.4Lor1 mol of N2 in 44.8 L. (d) CH;OH(I) or CH3ОH (s).
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Please help me answer question 19.39 show work if any. Thank you very much
![### Entropy and Microstates
**Exercise 19.39**
For each of the following pairs, predict which substance has the higher entropy per mole at a given temperature:
- **(a)** I₂(s) or I₂(g)
- **(b)** O₂(g) at 50.7 kPa or O₂ at 101.3 kPa
- **(c)** CO₂(g) and Ar(g) have nearly the same molar mass. At a given temperature, they will have the same number of microstates.
- **(d)** CH₃OH(l) or CH₃OH(s)
**Exercise 19.40**
For each of the following, predict which substance possesses the larger entropy per mole:
- **(a)** 1 mol of O₂(g) at 300°C, 1.013 kPa, or 1 mol of O₂(g) at 300°C, 101.3 kPa.
- **(b)** 1 mol of H₂O(g) at 300°C, 101.3 kPa, or 1 mol of H₂O(l) at 100°C, 101.3 kPa.
- **(c)** 0.5 mol of N₂(g) at 298 K, 20-L volume, or 0.5 mol CH₃OH(l) at 298 K.
- **(d)** 100 g of Na₂SO₄(s) at 100°C or 100 g of Na₂SO₄(aq) at 30°C.
**Exercise 19.41**
Predict the sign of the entropy change of the system for each of the following reactions:
[End of transcription]
### Explanation:
The text discusses exercises related to entropy, a measure of disorder or randomness in a system. Students are asked to compare the entropy of different substances or conditions, predicting which has a higher entropy based on factors like state of matter (solid, liquid, gas), pressure, temperature, and chemical composition. This helps in understanding how entropy changes in physical and chemical processes.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F6ef85c79-8e8f-4d9a-890a-b67fe0c4488a%2F562ca88c-5502-45f9-8798-bf641f2dd840%2F1vaf8oi_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Entropy and Microstates
**Exercise 19.39**
For each of the following pairs, predict which substance has the higher entropy per mole at a given temperature:
- **(a)** I₂(s) or I₂(g)
- **(b)** O₂(g) at 50.7 kPa or O₂ at 101.3 kPa
- **(c)** CO₂(g) and Ar(g) have nearly the same molar mass. At a given temperature, they will have the same number of microstates.
- **(d)** CH₃OH(l) or CH₃OH(s)
**Exercise 19.40**
For each of the following, predict which substance possesses the larger entropy per mole:
- **(a)** 1 mol of O₂(g) at 300°C, 1.013 kPa, or 1 mol of O₂(g) at 300°C, 101.3 kPa.
- **(b)** 1 mol of H₂O(g) at 300°C, 101.3 kPa, or 1 mol of H₂O(l) at 100°C, 101.3 kPa.
- **(c)** 0.5 mol of N₂(g) at 298 K, 20-L volume, or 0.5 mol CH₃OH(l) at 298 K.
- **(d)** 100 g of Na₂SO₄(s) at 100°C or 100 g of Na₂SO₄(aq) at 30°C.
**Exercise 19.41**
Predict the sign of the entropy change of the system for each of the following reactions:
[End of transcription]
### Explanation:
The text discusses exercises related to entropy, a measure of disorder or randomness in a system. Students are asked to compare the entropy of different substances or conditions, predicting which has a higher entropy based on factors like state of matter (solid, liquid, gas), pressure, temperature, and chemical composition. This helps in understanding how entropy changes in physical and chemical processes.
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