18.44 (a) Calculate the specific heat at constant volume of water vapor, assuming the nonlinear triatomic molecule has three transla- tional and three rotational degrees of freedom and that vibrational motion does not contribute. The molar mass of water is 18.0 g/mol. (b) The actual specific heat of water vapor at low pres- sures is about 2000 J/kg K. Compare this with your calculation and comment on the actual role of vibrational motion.

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University physic : Thermal Properties of Matter ( Hand writting Please)

18.44 (a) Calculate the specific heat at constant volume of water
vapor, assuming the nonlinear triatomic molecule has three transla-
tional and three rotational degrees of freedom and that vibrational
motion does not contribute. The molar mass of water is
18.0 g/mol. (b) The actual specific heat of water vapor at low pres-
sures is about 2000 J/kg. K. Compare this with your calculation
and comment on the actual role of vibrational motion.
Transcribed Image Text:18.44 (a) Calculate the specific heat at constant volume of water vapor, assuming the nonlinear triatomic molecule has three transla- tional and three rotational degrees of freedom and that vibrational motion does not contribute. The molar mass of water is 18.0 g/mol. (b) The actual specific heat of water vapor at low pres- sures is about 2000 J/kg. K. Compare this with your calculation and comment on the actual role of vibrational motion.
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