18.44 (a) Calculate the specific heat at constant volume of water vapor, assuming the nonlinear triatomic molecule has three transla- tional and three rotational degrees of freedom and that vibrational motion does not contribute. The molar mass of water is 18.0 g/mol. (b) The actual specific heat of water vapor at low pres- sures is about 2000 J/kg K. Compare this with your calculation and comment on the actual role of vibrational motion.
18.44 (a) Calculate the specific heat at constant volume of water vapor, assuming the nonlinear triatomic molecule has three transla- tional and three rotational degrees of freedom and that vibrational motion does not contribute. The molar mass of water is 18.0 g/mol. (b) The actual specific heat of water vapor at low pres- sures is about 2000 J/kg K. Compare this with your calculation and comment on the actual role of vibrational motion.
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