18 Lổ -H 8. H-SO4 →(A). Product (A) of the reaction is : 018 (a) Ph – NH –C-Ph (b) Ph – NH –C -Ph OH (c) (Ph)2 –Ċ –NH2 (d) Ph – CH2 – NH – Ph

Chemistry
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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**Question 8:**

Given the reaction:

\[ 
\text{(Diagram of a chemical compound)}
\]

The initial compound features a nitrogen atom double-bonded to carbon, with the carbon atom connected to two phenyl groups (benzene rings). An 18-oxygen isotopic hydroxy group (O-H) is also present.

**Reagents:**

- \( \text{H}_2\text{SO}_4 \)
- \( \text{H}_2^{18}\text{O} \)

The reaction proceeds to generate a product labeled as (A).

**Question: Which is the Product (A) of the reaction?**

**Options:**

(a) \( \text{Ph} - \text{NH} - \underset{OH}{\overset{||}{\text{C}}} - \text{Ph} \)

(b) \( \text{Ph} - \text{NH} - \overset{18}{=}\text{C} - \text{Ph} \)

(c) \( (\text{Ph})_2 - \text{C} - \text{NH}_2 \)

(d) \( \text{Ph} - \text{CH}_2 - \text{NH} - \text{Ph} \)

**Explanation of Reaction Context:**

The reaction involves isotopic labeling with oxygen-18 in the presence of sulfuric acid and isotopically labeled water. The transformation under these conditions will affect the structure in relation to the nitrogen and possibilities for exchange or rearrangement involving the oxygen isotope.

**Note:** Ph is a phenyl group, a common representation for a benzene ring attached to a carbon chain.
Transcribed Image Text:**Question 8:** Given the reaction: \[ \text{(Diagram of a chemical compound)} \] The initial compound features a nitrogen atom double-bonded to carbon, with the carbon atom connected to two phenyl groups (benzene rings). An 18-oxygen isotopic hydroxy group (O-H) is also present. **Reagents:** - \( \text{H}_2\text{SO}_4 \) - \( \text{H}_2^{18}\text{O} \) The reaction proceeds to generate a product labeled as (A). **Question: Which is the Product (A) of the reaction?** **Options:** (a) \( \text{Ph} - \text{NH} - \underset{OH}{\overset{||}{\text{C}}} - \text{Ph} \) (b) \( \text{Ph} - \text{NH} - \overset{18}{=}\text{C} - \text{Ph} \) (c) \( (\text{Ph})_2 - \text{C} - \text{NH}_2 \) (d) \( \text{Ph} - \text{CH}_2 - \text{NH} - \text{Ph} \) **Explanation of Reaction Context:** The reaction involves isotopic labeling with oxygen-18 in the presence of sulfuric acid and isotopically labeled water. The transformation under these conditions will affect the structure in relation to the nitrogen and possibilities for exchange or rearrangement involving the oxygen isotope. **Note:** Ph is a phenyl group, a common representation for a benzene ring attached to a carbon chain.
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