16.55 Verify that each of the mechanisms (16.60), (16.61), and (16.62) gives r = k[NO]²[0₂]. Note: gas-phase reaction 2NO + O₂ → 2NO₂ 2NO N₂O₂ equilib. N₂O₂ + O₂ → 2NO₂ slow NO + 0₂ — NO3 NO3 + NO → 2NO₂ equilib. slow 2NO + O₂ → 2NO₂ (16.60) (16.61) (16.62)

Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
icon
Related questions
Question
16.55 Verify that each of the mechanisms (16.60), (16.61),
and (16.62) gives r = k[NO]²[0₂].
Note: gas-phase reaction 2NO+ O₂ → 2NO₂
2NO
N₂O2
equilib.
N₂O₂ + O₂ → 2NO₂
slow
NO + 0₂ — NO3
NO3 + NO → 2NO₂2
equilib.
slow
2NO+ O₂ → 2NO₂
(16.60)
(16.61)
(16.62)
Transcribed Image Text:16.55 Verify that each of the mechanisms (16.60), (16.61), and (16.62) gives r = k[NO]²[0₂]. Note: gas-phase reaction 2NO+ O₂ → 2NO₂ 2NO N₂O2 equilib. N₂O₂ + O₂ → 2NO₂ slow NO + 0₂ — NO3 NO3 + NO → 2NO₂2 equilib. slow 2NO+ O₂ → 2NO₂ (16.60) (16.61) (16.62)
Expert Solution
steps

Step by step

Solved in 3 steps

Blurred answer
Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Process Dynamics and Control, 4e
Process Dynamics and Control, 4e
Chemical Engineering
ISBN:
9781119285915
Author:
Seborg
Publisher:
WILEY
Industrial Plastics: Theory and Applications
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The