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16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. N(CH3)3 deact CH,N(CH3)3 A meta N(CH,)2 -CH3 act act

16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. N(CH3)3 deact CH,N(CH3)3 A meta N(CH,)2 -CH3 act act

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Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Question 16.46

s on 16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. the ху- the nan -CH,N(CH,), N(CH3)3 deact A meta В ng agents. N(CH,), CH3 act act ol P D
Transcribed Image Text:s on 16.46 Rank the following compounds in order of increasing reactivity in electrophilic bromination. In each case, indi- cate whether the principal monobromination products will be the ortho and para isomers or the meta isomer, and whether the compound will be more or less reactive than benzene. Explain carefully the points that cause any uncertainty. the ху- the nan -CH,N(CH,), N(CH3)3 deact A meta В ng agents. N(CH,), CH3 act act ol P D
Expert Solution
Step 1

The availability of lone pairs on N-atom makes it more reactive while the presence of positive charge on N-atom will inactivates the ring for electrophilic type of substitution.

The activated groups will generally direct the electrophile to para and ortho positions.

 

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