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- A) Write the mechanism and predict the products for the following reaction. Label each product as the thermodynamic product or the kinetic product. Write a few sentences explaining which product would predominate at low temperature and which would predominate at high temperature and explain the reason for this result. HBr ABd B) Choose reagents that would give the following product in a Diels-Alder reaction: C) Predict the major and minor product for the following Diels-Alder reaction:6) Provide the enantiomeric Diels-Alder adducts that would form from the following reaction along with the two transition states leading to them: + HO₂C2) Rank the following dienes in order of increasing rate of Diels-Alder reaction with maleic anhydride. You do not need to explain your ranking. H3C. H3CO Diene A Diene B Diene C
- (C) Provide the starting materials (diene and dienophile) necessary to form the ind product through a Diels-Alder reaction (beware of the stereochemical information). (a) (b) (c) (d) - Diene - Dienophile- Diene Dienophile - Diene + Dienophile- -Diene Dienophile- A Dor Br Br A ✓ CO₂Me CO₂Me A 4 A MeO CNPredict the products of the following Diels-Alder reaction.Please make your drawings clear! Thank you so much
- Draw the TWO possible products of the Diels-Alder reaction shown below.A chemist is attempting to synthesize a complex natural product with a highly strained cyclohexene ring system. Which type of reactants would be most suitable for achieving this goal, and why? Provide a detailed explanation of the choice of reactants and the expected outcome in terms of the Diels-Alder reaction.Which of the following will not act as diene reactant in a Diels Alder reaction? A) B) D) OCH3 H,CO A
- 2) Predict the major product for each Diels-Alder reaction. Include stereochemistry where appropriate. H. C=N (a) H H. CH3 CH;O, (b) Ph (c) Ph[Review Topics] [References] Draw structural formulas for the diene and dienophile that combine in a Diels-Alder reaction to form the product shown. Diene + Dienophile CH3O CH₂ I wwwwwwwThe Diels-Alder reaction is not limited to making six-membered rings with only carbon atoms. Predict the products of the following reaction that produce rings with atoms other than carbon in them.
