15.64 Calculate the pH of a buffer solution that is 0.20 M in HCN and 0.12 M in NaCN. Will the pH change if the solution is diluted by a factor of 2? Explain.
Ionic Equilibrium
Chemical equilibrium and ionic equilibrium are two major concepts in chemistry. Ionic equilibrium deals with the equilibrium involved in an ionization process while chemical equilibrium deals with the equilibrium during a chemical change. Ionic equilibrium is established between the ions and unionized species in a system. Understanding the concept of ionic equilibrium is very important to answer the questions related to certain chemical reactions in chemistry.
Arrhenius Acid
Arrhenius acid act as a good electrolyte as it dissociates to its respective ions in the aqueous solutions. Keeping it similar to the general acid properties, Arrhenius acid also neutralizes bases and turns litmus paper into red.
Bronsted Lowry Base In Inorganic Chemistry
Bronsted-Lowry base in inorganic chemistry is any chemical substance that can accept a proton from the other chemical substance it is reacting with.
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**Buffer Capacity Exercises**
**15.62**
Evaluate the pH change when equal volumes of the two solutions are mixed:
- (a) 0.10 M NH₃ and 0.10 M HCl
- (b) 100 mL of 0.10 M HCl and 0.10 M NaOH
**15.63**
Which of the following buffer solutions has the greater buffer capacity?
- (a) 50 mL of 0.30 M HNO₂-0.30 M NaNO₂
- (b) 50 mL of 0.40 M NH₄Br-0.60 M NH₃
**15.64**
Calculate the pH of a buffer solution that is 0.20 M in HCN and 0.12 M in NaCN. Will the pH change if the solution is diluted by a factor of 2? Explain.
**15.65**
Calculate the pH of a buffer solution prepared by dissolving 4.2 g of NaHCO₃ and 5.3 g of Na₂CO₃ in 0.20 L of water. Will the pH change if the solution volume is increased by a factor of 10? Explain.
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*Explanation*: The exercises focus on understanding buffer solutions, which resist changes in pH when small amounts of acids or bases are added. Exercises probe into the effect of dilution and concentration on buffer capacity and pH, encouraging the application of the Henderson-Hasselbalch equation for calculating pH."
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