15. What is the product, W, of the following reactionsequence?1 equiv.ICOzHi. excess NaOEtii. BriIV1 equiv.HO₂C.OHBrIIIV17. Predict the product of the followingreaction sequence.i. NaOC₂H5ii. CH3CH₂CH₂Briii. NaOHiv. H3O*, heatiii H30heatCO₂HOH?CO₂HOHJu qe jeOHOIIIIIIVWCOOHIII16. What would be the majorproduct of the following reactionsequence?OHa)Ethyl acetoacetateb)Ethyl acetoacetatec)Ethyl acetoacetateIVe)Ethyl hexanoatePCCCH₂Cl₂18. 2-Heptanone can be synthesized bywhich reaction sequence?heat,IINaOEt CH3(CH₂) 3 BrEtOHNaOEtEtOHi. dil.OH heatii. H30d)Ethyl acetoacetate CH₂(CH₂);Br_i. LDAii. C₂H₂I22i. NaOEt, EtOHii. CH3COCIVIIINaOEtEtOHi. dil.OH heatii. H30CH3(CH₂)3BrCH₂(CH₂), Bri. dil.OHii. H30¹heat,i. dil.OH heat_ii. H30*

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Answered: 15. What is the product, W, of the…

15. What is the product, W, of the following reaction sequence? 1 equiv. I -COzH i. excess NaOEt ii. Br IV 1 equiv. HO₂C. OH Br II iii H₂O heat CO₂H D-CO,H V W COOH III

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

15. What is the product, W, of the following reaction
sequence?
1 equiv.
I
COzH
i. excess NaOEt
ii. Bri
IV
1 equiv.
HO₂C.
OH
Br
II
IV
17. Predict the product of the following
reaction sequence.
i. NaOC₂H5
ii. CH3CH₂CH₂Br
iii. NaOH
iv. H3O*, heat
iii H30
heat
CO₂H
OH
?
CO₂H
OH
Ju qe je
OH
O
I
II
III
V
W
COOH
III
16. What would be the major
product of the following reaction
sequence?
OH
a)
Ethyl acetoacetate
b)
Ethyl acetoacetate
c)
Ethyl acetoacetate
IV
e)
Ethyl hexanoate
PCC
CH₂Cl₂
18. 2-Heptanone can be synthesized by
which reaction sequence?
heat,
II
NaOEt CH3(CH₂) 3 Br
EtOH
NaOEt
EtOH
i. dil.OH heat
ii. H30
d)
Ethyl acetoacetate CH₂(CH₂);Br_
i. LDA
ii. C₂H₂I
22
i. NaOEt, EtOH
ii. CH3COCI
V
III
NaOEt
EtOH
i. dil.OH heat
ii. H30
CH3(CH₂)3Br
CH₂(CH₂), Br
i. dil.OH
ii. H30¹
heat,
i. dil.OH heat_
ii. H30*

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