**Thermodynamics and Chemical Equilibrium Concepts****Problem 15:**At the boiling point, the liquid and vapor states are in equilibrium. What is the boiling point of benzene if \(\Delta H_{\text{vap}} = 30.7 \, \text{kJ/mol}\) and \(\Delta S_{\text{vap}} = 87.0 \, \text{J/mol} \cdot \text{K}\)? (Hint: What is \(\Delta G\) at equilibrium?)**Problem 16:**At \(700 \, \text{K}\), \(K_p = 6.7 \times 10^4\) for the reaction:\[ \text{2SO}_2(g) + \text{O}_2(g) \rightleftharpoons \text{2SO}_3(g) \]Determine at this temperature:a) \(\Delta G^\circ\) (in \(\text{kJ/mol}\))b) \(\Delta G\) (in \(\text{kJ/mol}\)) for a mixture consisting of 0.250 atm of \(\text{SO}_2\), 0.150 atm of \(\text{O}_2\), and 0.0563 atm of \(\text{SO}_3\).**Analysis:**- Problem 15 involves calculating the boiling point of benzene using the relationship between enthalpy (\(\Delta H\)), entropy (\(\Delta S\)), and Gibbs free energy (\(\Delta G\)).- Problem 16 focuses on applying the concept of chemical equilibrium and free energy change for a reaction in terms of partial pressures and the equilibrium constant \(K_p\).**Note:** There are no graphs or diagrams present that require explanation.

15. Given that, for benzeneThe = 30.7 kJ/mol = 30700 J/mol.The = 87.0 J/mol.K.We have to calculate…

Answered: [15] At the boiling point the liquid…

[15] At the boiling point the liquid and vapor states are in equilibrium. What is the boiling point of benzene if AHvap = 30.7 kJ/mol and ASvap = 87.0 J/mol-K? (Hint what is AG at equilibrium)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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