14,402 g Mass of glass bulb with the unknown gas: Mass empty bulb Temperature Volume of glass bulb: 670. mL Pressure 12.232 g 1751. tor 21.C The gas is A,3 8.) (a)Which of the four substances (A, B, C, or D) has the strongest intermolecular forces? (b) How do you know? 800 700 so0 500 400 300 300 300 c) What is the normal boiling point of substance A? O0 2 30
Ideal and Real Gases
Ideal gases obey conditions of the general gas laws under all states of pressure and temperature. Ideal gases are also named perfect gases. The attributes of ideal gases are as follows,
Gas Laws
Gas laws describe the ways in which volume, temperature, pressure, and other conditions correlate when matter is in a gaseous state. The very first observations about the physical properties of gases was made by Robert Boyle in 1662. Later discoveries were made by Charles, Gay-Lussac, Avogadro, and others. Eventually, these observations were combined to produce the ideal gas law.
Gaseous State
It is well known that matter exists in different forms in our surroundings. There are five known states of matter, such as solids, gases, liquids, plasma and Bose-Einstein condensate. The last two are known newly in the recent days. Thus, the detailed forms of matter studied are solids, gases and liquids. The best example of a substance that is present in different states is water. It is solid ice, gaseous vapor or steam and liquid water depending on the temperature and pressure conditions. This is due to the difference in the intermolecular forces and distances. The occurrence of three different phases is due to the difference in the two major forces, the force which tends to tightly hold molecules i.e., forces of attraction and the disruptive forces obtained from the thermal energy of molecules.
mass of the unknown gas, m = 14.402 - 12.232 = 2.17 g
T = 21oC = 21 +273.15 = 294.15 K
volume , V= 670 mL = 0.67L
Pressure, P = 1751 torr = 2.3039 atm
since 1atm = 760 torr
R = 0.0821 L atm mol-1K-1
use ideal gas equation to find molar mass,
M = = = 33.9495 g/mol ~ 34g/mol
Therefore the unknown gas is H2O2 , hydrogen peroxide.
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