14.5 The following table lists molecular weight data O for a polytetrafluoroethylene material. Compute the following: (a) the number-average molecular weight (b) the weight-average molecular weight (c) the degree of polymerization Molecular Weight Range (g/mol) X; W; 10,000-20,000 0.03 0.01 20,000-30,000 0.09 0.04 30,000-40,000 0.15 0.11 40,000-50,000 0.25 0.23 50,000-60,000 0.22 0.24 60,000-70,000 0.14 0.18 70,000-80,000 0.08 0.12 80,000-90,000 0.04 0.07
14.5 The following table lists molecular weight data O for a polytetrafluoroethylene material. Compute the following: (a) the number-average molecular weight (b) the weight-average molecular weight (c) the degree of polymerization Molecular Weight Range (g/mol) X; W; 10,000-20,000 0.03 0.01 20,000-30,000 0.09 0.04 30,000-40,000 0.15 0.11 40,000-50,000 0.25 0.23 50,000-60,000 0.22 0.24 60,000-70,000 0.14 0.18 70,000-80,000 0.08 0.12 80,000-90,000 0.04 0.07
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![### Molecular Weight Analysis of Polytetrafluoroethylene
The following table provides molecular weight data for a polytetrafluoroethylene material. You are asked to compute:
(a) The number-average molecular weight
(b) The weight-average molecular weight
(c) The degree of polymerization
#### Table: Molecular Weight Distribution
| Molecular Weight Range (g/mol) | \( x_i \) | \( w_i \) |
|----------------------------------|-----------|-----------|
| 10,000–20,000 | 0.03 | 0.01 |
| 20,000–30,000 | 0.09 | 0.04 |
| 30,000–40,000 | 0.15 | 0.11 |
| 40,000–50,000 | 0.25 | 0.23 |
| 50,000–60,000 | 0.22 | 0.24 |
| 60,000–70,000 | 0.14 | 0.18 |
| 70,000–80,000 | 0.06 | 0.12 |
| 80,000–90,000 | 0.04 | 0.07 |
- **\( x_i \)** represents the mole fraction.
- **\( w_i \)** denotes the weight fraction.
To compute the number-average molecular weight, \( M_n \):
\[ M_n = \frac{\Sigma (x_i M_i)}{\Sigma x_i} \]
For the weight-average molecular weight, \( M_w \):
\[ M_w = \frac{\Sigma (w_i M_i)}{\Sigma w_i} \]
The degree of polymerization can be calculated using:
\[ \text{Degree of Polymerization} = \frac{M_n}{M_0} \]
Where \( M_0 \) is the molecular weight of the monomer unit.
These computations will help characterize the polymer's molecular distribution, affecting its physical and chemical properties.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Ff2520f39-8b3c-4b2b-be15-831ac0e5241f%2Fc30c2dc6-4a66-43f3-beea-04a58afa7caa%2Fg55xhok_processed.jpeg&w=3840&q=75)
Transcribed Image Text:### Molecular Weight Analysis of Polytetrafluoroethylene
The following table provides molecular weight data for a polytetrafluoroethylene material. You are asked to compute:
(a) The number-average molecular weight
(b) The weight-average molecular weight
(c) The degree of polymerization
#### Table: Molecular Weight Distribution
| Molecular Weight Range (g/mol) | \( x_i \) | \( w_i \) |
|----------------------------------|-----------|-----------|
| 10,000–20,000 | 0.03 | 0.01 |
| 20,000–30,000 | 0.09 | 0.04 |
| 30,000–40,000 | 0.15 | 0.11 |
| 40,000–50,000 | 0.25 | 0.23 |
| 50,000–60,000 | 0.22 | 0.24 |
| 60,000–70,000 | 0.14 | 0.18 |
| 70,000–80,000 | 0.06 | 0.12 |
| 80,000–90,000 | 0.04 | 0.07 |
- **\( x_i \)** represents the mole fraction.
- **\( w_i \)** denotes the weight fraction.
To compute the number-average molecular weight, \( M_n \):
\[ M_n = \frac{\Sigma (x_i M_i)}{\Sigma x_i} \]
For the weight-average molecular weight, \( M_w \):
\[ M_w = \frac{\Sigma (w_i M_i)}{\Sigma w_i} \]
The degree of polymerization can be calculated using:
\[ \text{Degree of Polymerization} = \frac{M_n}{M_0} \]
Where \( M_0 \) is the molecular weight of the monomer unit.
These computations will help characterize the polymer's molecular distribution, affecting its physical and chemical properties.
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