14. Rank the following molecules in order of increasing relative rate of SN1 solvolysis with methanol and heat (slowest to fastest reacting). Br Br Br CH3 CH3 CH3 CH3 H3C Br 1 2 3 A) 3 < 2 < 4 < 5<1 D) 2 < 3 < 4 < 5 <1 B) 2 < 3 < 4 < 1<5 E) 1 < 2 < 5 < 4 < 3 C) 5 < 4 < 3 < 2 < 1
14. Rank the following molecules in order of increasing relative rate of SN1 solvolysis with methanol and heat (slowest to fastest reacting). Br Br Br CH3 CH3 CH3 CH3 H3C Br 1 2 3 A) 3 < 2 < 4 < 5<1 D) 2 < 3 < 4 < 5 <1 B) 2 < 3 < 4 < 1<5 E) 1 < 2 < 5 < 4 < 3 C) 5 < 4 < 3 < 2 < 1
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Chapter1: Chemical Foundations
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Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Question 14: Ranking Molecules by SN1 Solvolysis Reactivity**
The task is to rank the given molecules in order of increasing relative rate of SN1 solvolysis with methanol and heat, from slowest to fastest reacting.
**Molecular Structures:**
1. **Molecule 1:** Cyclohexane ring with a methyl group (CH₃) and a bromine (Br) attached.
2. **Molecule 2:** Cyclohexane ring with a methyl group (CH₃) and a bromine (Br) attached at different positions.
3. **Molecule 3:** Cyclohexane ring with a methyl group (CH₃) and a chlorine (Cl) attached.
4. **Molecule 4:** Cyclohexane ring with a methyl group (CH₃) and a bromine (Br) attached at a different position.
5. **Molecule 5:** Bromine (Br) attached to a cyclohexane ring with a two-carbon alkyl group (CH₂CH₃).
**Answer Options:**
A) 3 < 2 < 4 < 5 < 1
B) 2 < 3 < 4 < 1 < 5
C) 5 < 4 < 3 < 2 < 1
D) 2 < 3 < 4 < 5 < 1
E) 1 < 2 < 5 < 4 < 3
Select the correct order that ranks the molecules according to their increasing reactivity in the SN1 solvolysis process.
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