13.84 For the water-gas shift reaction CO(g) + H2O(g) = CO2(g) + H2(g), AH° = in an equilibrium mixture increase or decrease when the temperature is increased? How does K. change when the temperature is decreased? Justify your answers using Le Châtelier's principle. -41.2 kJ, does the amount of H2

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
icon
Related questions
icon
Concept explainers
Question

Can you please answer question 13.84 and show all of the steps to the solution 

# Le Châtelier's Principle (Sections 13.6–13.10)

## 13.80
Consider the following equilibrium: \( \text{Ag}^+(aq) + \text{Cl}^-(aq) \rightleftharpoons \text{AgCl}(s) \). Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by:

(a) Adding NaCl  
(b) Adding AgNO\(_3\)  
(c) Adding NH\(_3\), which reacts with Ag\(^+\) to form the complex ion \( \text{Ag(NH}_3\text{)}_2^+ \)  
(d) Removing Cl\(^-\); also account for the change using the reaction quotient Q\(_c\).

## 13.81
Will the concentration of NO\(_2\) increase, decrease, or remain the same when the equilibrium \( \text{NOCl}(g) + \text{NO}_2(g) \rightleftharpoons \text{NOCl}(g) + \text{NO}_2(g) \) is disturbed by the following changes?

(a) Adding NOCl  
(b) Adding NO  
(c) Removing NO  
(d) Adding NO\(_2\)Cl; also account for the change using the reaction quotient Q\(_c\).

## 13.82
When each of the following equilibria is disturbed by increasing the pressure as a result of decreasing the volume, does the number of moles of reaction products increase, decrease, or remain the same?

(a) \( 2\text{CO}(g) \rightleftharpoons 2\text{CO}(g) + \text{O}_2(g) \)  
(b) \( \text{N}_2(g) + 2\text{Cl}_2(g) \rightleftharpoons 2\text{NOCl}(g) \)  
(c) \( \text{Si}(s) + 2\text{Cl}_2(g) \rightleftharpoons \text{SiCl}_4(g) \)

## 13.83
For each of the following equilibria, use Le Châtelier's principle to predict the direction of reaction when the volume is increased.

(a) \( \text{C}(s) + \text
Transcribed Image Text:# Le Châtelier's Principle (Sections 13.6–13.10) ## 13.80 Consider the following equilibrium: \( \text{Ag}^+(aq) + \text{Cl}^-(aq) \rightleftharpoons \text{AgCl}(s) \). Use Le Châtelier's principle to predict how the amount of solid silver chloride will change when the equilibrium is disturbed by: (a) Adding NaCl (b) Adding AgNO\(_3\) (c) Adding NH\(_3\), which reacts with Ag\(^+\) to form the complex ion \( \text{Ag(NH}_3\text{)}_2^+ \) (d) Removing Cl\(^-\); also account for the change using the reaction quotient Q\(_c\). ## 13.81 Will the concentration of NO\(_2\) increase, decrease, or remain the same when the equilibrium \( \text{NOCl}(g) + \text{NO}_2(g) \rightleftharpoons \text{NOCl}(g) + \text{NO}_2(g) \) is disturbed by the following changes? (a) Adding NOCl (b) Adding NO (c) Removing NO (d) Adding NO\(_2\)Cl; also account for the change using the reaction quotient Q\(_c\). ## 13.82 When each of the following equilibria is disturbed by increasing the pressure as a result of decreasing the volume, does the number of moles of reaction products increase, decrease, or remain the same? (a) \( 2\text{CO}(g) \rightleftharpoons 2\text{CO}(g) + \text{O}_2(g) \) (b) \( \text{N}_2(g) + 2\text{Cl}_2(g) \rightleftharpoons 2\text{NOCl}(g) \) (c) \( \text{Si}(s) + 2\text{Cl}_2(g) \rightleftharpoons \text{SiCl}_4(g) \) ## 13.83 For each of the following equilibria, use Le Châtelier's principle to predict the direction of reaction when the volume is increased. (a) \( \text{C}(s) + \text
Expert Solution
steps

Step by step

Solved in 2 steps with 1 images

Blurred answer
Knowledge Booster
Ionic Equilibrium
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemistry and related others by exploring similar questions and additional content below.
Recommended textbooks for you
Chemistry
Chemistry
Chemistry
ISBN:
9781305957404
Author:
Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:
Cengage Learning
Chemistry
Chemistry
Chemistry
ISBN:
9781259911156
Author:
Raymond Chang Dr., Jason Overby Professor
Publisher:
McGraw-Hill Education
Principles of Instrumental Analysis
Principles of Instrumental Analysis
Chemistry
ISBN:
9781305577213
Author:
Douglas A. Skoog, F. James Holler, Stanley R. Crouch
Publisher:
Cengage Learning
Organic Chemistry
Organic Chemistry
Chemistry
ISBN:
9780078021558
Author:
Janice Gorzynski Smith Dr.
Publisher:
McGraw-Hill Education
Chemistry: Principles and Reactions
Chemistry: Principles and Reactions
Chemistry
ISBN:
9781305079373
Author:
William L. Masterton, Cecile N. Hurley
Publisher:
Cengage Learning
Elementary Principles of Chemical Processes, Bind…
Elementary Principles of Chemical Processes, Bind…
Chemistry
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY