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- 17.39 Using ethanol as the source of all the carbon atoms, describe efficient syntheses of each of the following, using any necessary organic or inorganic reagents: (a) CH3CH(OCH2CH3)2 (b) H CH317.39 Using ethanol as the source of all the carbon atoms, describe efficient syntheses of each of the following, using any necessary organic or inorganic reagents: (c) O (d) CH3CHC=CH OH10.23 Show, by writing a suitable sequence of chemical equations, how you could prepare the following compound from cyclopentene and any necessary organic or inorganic reagents: (a) 2-Cyclopenten-1-ol
- 17.36 How would you carry out the following transformations? CO,H CO,H (a) CO,H CH,OH (b)8.30 Outline an efficient synthesis of each of the following compounds from the indicated starting material and any necessary organic or inorganic reagents: (g) Isopropyl azide from isopropyl alcohol (h) Isopropyl azide from 1-propanol (i) (S)-sec-butyl azide from (R)-sec-butyl alcohol8.30 Outline an efficient synthesis of each of the following compounds from the indicated starting material and any necessary organic or inorganic reagents: (d) NCCH2CH2CN from ethyl alcohol (e) Isobutyl iodide from isobutyl chloride (f) Isobutyl iodine from tert-butyl chloride
- 18.26 Predict the products of the following ether cleavage reactions: LOCH CH3 OC(CH3)3 (a) HI CF3CO,H, ? (b) H2O HI HI (c) Н,С— СНОСH,CH, (d) (CH3);CCH,OCH,CH3 H20 H2O17.39 Using ethanol as the source of all the carbon atoms, describe efficient syntheses of each of the following, using any necessary organic or inorganic reagents: (e) HCCH₂C=CH (f) CH3CH2CH2CH₂OH15.37 Write mechanisms that account for the products of the following reactions: (a) (b) 15.37 Write mechanisms that account for the products of the following reactions: (a) OH HA (-H₂O) HA (b)
- 19.73 Propose an efficient synthesis for each of the following transformations: (a) 0-0 (b) (c) Br -11.4 Show how are the following alcohols prepared by the reaction of a suitable Grignard reagent on methanal ? CH,OH () CH, CH-CH,ОН CH, (ii)Which of the following is the major product of the reaction below? (1) LDA/ether (2) (3) ethanol, A (A) (B) (C) (D) OCompound A Compound D Compound B Compound C
