13.2 How many peaks in the 13C-NMR spectrum? F דו F

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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How many peaks in the C-NMR spectrum?

**Title: Understanding ¹³C-NMR Spectrum Peaks**

**Question: 13.2 How many peaks in the ¹³C-NMR spectrum?**

**Description:**

In this exercise, we're examining the molecular structure of a difluorocyclohexane compound to determine how many distinct peaks appear in its ¹³C-NMR spectrum.

**Molecular Structure:**

The diagram illustrates a cyclohexane ring with two fluorine atoms. One fluorine atom is attached to the top carbon, and the other is attached to the bottom right carbon. These are shown using wedge bonds, indicating a three-dimensional configuration.

**Analysis:**

The presence and position of the fluorine atoms on the cyclohexane ring impact the chemical shifts of the carbon atoms in the NMR spectrum. In ¹³C-NMR, each unique carbon environment in a molecule gives rise to a separate peak. Because of the symmetry and substitution pattern in this molecule, identify how many unique carbon environments are present to determine the number of peaks.

**Conclusion:**

Assess the symmetry and carbon environments to conclude how many peaks will be observed in the ¹³C-NMR spectrum for this difluorocyclohexane molecule.
Transcribed Image Text:**Title: Understanding ¹³C-NMR Spectrum Peaks** **Question: 13.2 How many peaks in the ¹³C-NMR spectrum?** **Description:** In this exercise, we're examining the molecular structure of a difluorocyclohexane compound to determine how many distinct peaks appear in its ¹³C-NMR spectrum. **Molecular Structure:** The diagram illustrates a cyclohexane ring with two fluorine atoms. One fluorine atom is attached to the top carbon, and the other is attached to the bottom right carbon. These are shown using wedge bonds, indicating a three-dimensional configuration. **Analysis:** The presence and position of the fluorine atoms on the cyclohexane ring impact the chemical shifts of the carbon atoms in the NMR spectrum. In ¹³C-NMR, each unique carbon environment in a molecule gives rise to a separate peak. Because of the symmetry and substitution pattern in this molecule, identify how many unique carbon environments are present to determine the number of peaks. **Conclusion:** Assess the symmetry and carbon environments to conclude how many peaks will be observed in the ¹³C-NMR spectrum for this difluorocyclohexane molecule.
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